The oligomer of 1,6-naphthalenediol as a support in oxidative reactions of cis-bisglycinato copper(II) and hydrogenperoxide

被引:14
作者
Handique, JG [1 ]
Baruah, JB [1 ]
机构
[1] Indian Inst Technol, Dept Chem, N Guwahati 781039, India
关键词
oligomer; copper(II); hydrogenperoxide;
D O I
10.1016/S1381-1169(01)00117-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Oxidative oligomerization of 1,6-naphthalenediol by cis-bisglycinato copper(II)monohydrate with hydrogenperoxide gives C-O bonded oligomer. Further reactivity of this oligomer with hydrogen peroxide and organic substrate shows improvement in the yield of oxidative and hydrolytic reactions. For example the oligomer along with cis-bisglycinato copper(LT) catalyses hydrolytic reaction of benzamide to benzoic acid. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:19 / 23
页数:5
相关论文
共 22 条
[1]  
AYCOCK DV, 1988, ENCY POLYM SCI ENG, V13
[2]   Experimental studies of the interconversion of μ-η2:η2-peroxo- and bis(μ-oxo)dicopper complexes [J].
Cahoy, J ;
Holland, PL ;
Tolman, WB .
INORGANIC CHEMISTRY, 1999, 38 (09) :2161-2168
[3]  
Clark J.H., 1994, CATALYSIS ORGANIC RE
[4]  
Davidson D. W., 1984, INCLUSION COMPOUNDS, V3, P69
[5]   Reversible cleavage and formation of the dioxygen O-O band within a dicopper complex [J].
Halfen, JA ;
Mahapatra, S ;
Wilkinson, EC ;
Kaderli, S ;
Young, VG ;
Que, L ;
Zuberbuhler, AD ;
Tolman, WB .
SCIENCE, 1996, 271 (5254) :1397-1400
[6]   Oxidative oligomerisation of 2-naphthol by cis-bis(glycinato)copper(II) [J].
Handique, JG ;
Baruah, JB .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 166 (02) :225-231
[7]  
HARTLEY FR, 1985, SUPPORTED METALS COM
[8]   Novel cavity design using calix[n]arene skeletons: Toward molecular recognition and metal binding [J].
Ikeda, A ;
Shinkai, S .
CHEMICAL REVIEWS, 1997, 97 (05) :1713-1734
[9]  
ITO H, 1996, DESK REFERENCE FUNCT, P311
[10]  
Itoh S, 2000, ANGEW CHEM INT EDIT, V39, P398, DOI 10.1002/(SICI)1521-3773(20000117)39:2<398::AID-ANIE398>3.0.CO