(Vapour plus liquid) equilibria (VLE) of CO2 in aqueous solutions of 2-amino-2-methyl-1-propanol: New data and modelling using eNRTL-equation

被引：48

作者：

Dash, Sukanta Kumar ^{[1
]}

Samanta, Amar Nath ^{[2
]}

Bandyopadhyay, Syamalendu S. ^{[1
]}

机构：

[1] Indian Inst Technol, Separat Sci Lab, Cryogen Engn Ctr, Kharagpur 721302, W Bengal, India

[2] Indian Inst Technol, Dept Chem Engn, Kharagpur 721302, W Bengal, India

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 2011年 / 43卷 / 08期

关键词：

2-Amino-2-metyl-1-propanol; Carbon dioxide; (Vapour plus liquid) equilibria; Electrolyte NRTL; Modelling; CARBON-DIOXIDE; SOLUBILITY; ALKANOLAMINE; ABSORPTION; MIXTURES; ENTHALPY; KINETICS; AMINES; WATER; DIETHANOLAMINE;

D O I：

10.1016/j.jct.2011.03.016

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

This work presents new experimental results for carbon dioxide (CO2) solubility in aqueous 2-amino-2-methyl-1-propanol (AMP) over the temperature range of (298 to 328) K and CO2 partial pressure of about (0.4 to 1500) kPa. The concentrations of the aqueous AMP lie within the range of (2.2 to 4.9) mol . dm(-3). A thermodynamic model based on electrolyte non-random two-liquid (eNRTL) theory has been developed to correlate and predict the (vapour + liquid) equilibrium (VLE) of CO2 in aqueous AMP. The model predictions have been in good agreement with the experimental data of CO2 solubility in aqueous blends of this work as well as those reported in the literature. The current model can also predict speciation, heat of absorption, enthalpy of CO2 loaded aqueous AMP, pH of the loaded solution, and AMP volatility. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：1278 / 1285

页数：8

共 40 条

[1] Enthalpy of solution of CO2 in aqueous solutions of 2-amino-2-methyl-1-propanol [J].

Arcis, Hugues ;

Rodier, Laurence ;

Coxam, Jean-Yves .

JOURNAL OF CHEMICAL THERMODYNAMICS, 2007, 39 (06) :878-887

[2] Modeling of (vapor plus liquid) equilibrium and enthalpy of solution of carbon dioxide (CO2) in aqueous methyldiethanolamine (MDEA) solutions [J].

Arcis, Hugues ;

Rodier, Laurence ;

Ballerat-Busserolles, Karine ;

Coxam, Jean-Yves .

JOURNAL OF CHEMICAL THERMODYNAMICS, 2009, 41 (06) :783-789

[3]

Aspen Technology Inc, 2008, ASP PHYS PROP SYST V

[4] MODEL OF VAPOR LIQUID EQUILIBRIA FOR AQUEOUS ACID GAS ALKANOLAMINE SYSTEMS USING THE ELECTROLYTE NRTL EQUATION [J].

AUSTGEN, DM ;

ROCHELLE, GT ;

PENG, X ;

CHEN, CC .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1989, 28 (07) :1060-1073

[5] Ternary isobaric vapor-liquid equilibria of methanol plus N-methyldiethanolamine plus water and methanol plus 2-amino-2-methyl-1-propanol plus water systems [J].

Barreau, Alain ;

Mougin, Pascal ;

Lefebvre, Catherine ;

Thi, Quinn M. Luu ;

Rieu, Julien .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2007, 52 (03) :769-773

[6] A LOCAL COMPOSITION MODEL FOR THE EXCESS GIBBS ENERGY OF AQUEOUS-ELECTROLYTE SYSTEMS [J].

CHEN, CC ;

EVANS, LB .

AICHE JOURNAL, 1986, 32 (03) :444-454

[7] Removal of carbon dioxide by absorption into blended amines: kinetics of absorption into aqueous AMP/HMDA, AMP/MDEA, and AMP/piperazine solutions [J].

Choi, Won-Joon ;

Cho, Ki-Chul ;

Lee, Sang-Sup ;

Shim, Jae-Goo ;

Hwang, Hye-Ryun ;

Park, Sang-Wook ;

Oh, Kwang-Joong .

GREEN CHEMISTRY, 2007, 9 (06) :594-598

[8] Thermodynamics of aqueous potassium carbonate, piperazine, and carbon dioxide [J].

Cullinane, JT ;

Rochelle, GT .

FLUID PHASE EQUILIBRIA, 2005, 227 (02) :197-213

[9]

DASH SK, CHEM ENG SC IN PRESS, DOI DOI 10.1016/J.CES2011.02.028

[10] Vapour liquid equilibria of carbon dioxide in dilute and concentrated aqueous solutions of piperazine at low to high pressure [J].

Dash, Sukanta Kumar ;

Samanta, Arunkumar ;

Samanta, Amar Nath ;

Bandyopadhyay, Syamalendu S. .

FLUID PHASE EQUILIBRIA, 2011, 300 (1-2) :145-154

← 1 2 3 4 →