Direct synthesis of cinnamaldehyde derivatives by reaction of aryl bromides with 3,3-diacetoxypropene catalyzed by a palladium-tetraphosphine complex

被引：18

作者：

Berthiol, F

Doucet, H

Santelli, M

机构：

[1] Fac Sci & Tech St Jerome, Synth Organ Lab, CNRS, UMR 6180, F-13397 Marseille, France

[2] Univ Aix Marseille 3, F-13397 Marseille, France

来源：

CATALYSIS LETTERS | 2005年 / 102卷 / 3-4期

关键词：

palladium; tetraphosphine; catalysis; Heck reaction; aryl bromide;

D O I：

10.1007/s10562-005-5869-z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The tetraphosphine all-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane in combination with [Pd(C3H5)Cl](2) affords an efficient catalyst for the synthesis of cinnamaldehyde derivatives by reaction of aryl bromides with 3,3-diacetoxypropene. The reaction gave directly the cinnamaldehyde derivatives very selectively. The coupling reaction of heteroaryl bromides or sterically congested aryl bromides such as 2,4,6-trimethylbromobenzene also proceeds.

引用

页码：281 / 284

页数：4

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