Effects of H2 plasma and annealing on atomic-layer-deposited Al2O3 films and Al/Al2O3/Si structures

被引:15
作者
Choi, Kyeong-Keun [1 ]
Kee, Jong [1 ]
Park, Chan-Gyung [1 ]
Kim, Deok-kee [2 ]
机构
[1] Pohang Univ Sci & Technol POSTECH, NINT, Pohang 790784, Gyeongbuk, South Korea
[2] Sejong Univ, Dept Elect Engn, Seoul 143747, South Korea
基金
新加坡国家研究基金会;
关键词
SILICON;
D O I
10.7567/APEX.8.045801
中图分类号
O59 [应用物理学];
学科分类号
摘要
We evaluated the effects of H-2 plasma and thermal treatment on current-voltage (I-V) and capacitance-voltage ( C-V) characteristics using Al/Al2O3/Si. H-2 plasma treatment reduced the concentration of C and enhanced the diffusion of Si and O atoms and the mean breakdown field strength. The breakdown field increased significantly after rapid thermal annealing (RTA) due to crystallization and the formation of an interface layer between Si and Al2O3, which was confirmed by TEM, secondary ion mass spectroscopy (SIMS), and three-dimensional (3D) atom probe tomography. H-2 plasma treatment produced a negative fixed charge due to the outgassing of C and H-2, and RTA produced a positive fixed charge. (C) 2015 The Japan Society of Applied Physics
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页数:4
相关论文
共 22 条
[1]  
Benmalek M., SURF COATINGS TECHNO, p[76, 821]
[2]   Annealing effects of aluminum silicate films grown on Si(100) [J].
Cho, MH ;
Rho, YS ;
Choi, HJ ;
Nam, SW ;
Ko, KH ;
Ku, JH ;
Kang, HC ;
Noh, Y ;
Whang, CN ;
Jeong, K .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2002, 20 (03) :865-872
[3]   Effect of hydrogen remote plasma annealing on the characteristics of copper film [J].
Choi, KK ;
Yun, JH ;
Rhee, SW .
THIN SOLID FILMS, 2003, 429 (1-2) :255-260
[4]   Effect of Hydrogen Plasma on Electroless-Plating Ni-B Films and Its Cu Diffusion Barrier Property [J].
Choi, Kyeong-Keun ;
Kee, Jong ;
Kwon, Da-Jung ;
Kim, Deok-Kee .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2014, 14 (12) :9599-9605
[5]   Filling performance and electrical characteristics of Al2O3 films deposited by atomic layer deposition for through-silicon via applications [J].
Choi, Kyeong-Keun ;
Kee, Jong ;
Kim, Si-Hong ;
Park, Myung-Soo ;
Park, Chan-Gyung ;
Kim, Deok-Kee .
THIN SOLID FILMS, 2014, 556 :560-565
[6]   Impact of carbon and nitrogen impurities in high-κ dielectrics on metal-oxide-semiconductor devices [J].
Choi, Minseok ;
Lyons, John L. ;
Janotti, Anderson ;
Van de Walle, Chris G. .
APPLIED PHYSICS LETTERS, 2013, 102 (14)
[7]   Ultrahigh X-ray reflectivity from W/Al2O3 multilayers fabricated using atomic layer deposition -: art. no. 013116 [J].
Fabreguette, FH ;
Wind, RA ;
George, SM .
APPLIED PHYSICS LETTERS, 2006, 88 (01)
[8]   Electrical characterization of thin Al2O3 films grown by atomic layer deposition on silicon and various metal substrates [J].
Groner, MD ;
Elam, JW ;
Fabreguette, FH ;
George, SM .
THIN SOLID FILMS, 2002, 413 (1-2) :186-197
[9]   Low-temperature Al2O3 atomic layer deposition [J].
Groner, MD ;
Fabreguette, FH ;
Elam, JW ;
George, SM .
CHEMISTRY OF MATERIALS, 2004, 16 (04) :639-645
[10]   High-resolution depth profiling in ultrathin Al2O3 films on Si [J].
Gusev, EP ;
Copel, M ;
Cartier, E ;
Baumvol, IJR ;
Krug, C ;
Gribelyuk, MA .
APPLIED PHYSICS LETTERS, 2000, 76 (02) :176-178