Synthesis of hexagonal shape-persistent cyclophane with D2h symmetry

被引：4
作者：
Tagawa, Kazunari [1 ]
Mori, Shigeki [2 ]
Takase, Masayoshi [1 ]
Okujima, Tetsuo [1 ]
Hisaki, Ichiro [3 ]
Uno, Hidemitsu [1 ]
机构：
[1] Ehime Univ, Grad Sch Sci & Engn, Dept Biol & Chem, Matsuyama, Ehime 7908577, Japan
[2] Ehime Univ, Adv Res Support Ctr, Matsuyama, Ehime 7908577, Japan
[3] Osaka Univ, Grad Sch Engn, Suita, Osaka 5650871, Japan
来源：
TETRAHEDRON LETTERS | 2016年 / 57卷 / 36期
关键词：
Shape-persistent cyclophane; SNAr reaction; Bicyclo[2.2.2]octadiene-fused dipyrrole; Diethanotetrahydroanthracene-fused dipyrrole; X-ray analysis; MOLECULAR RECOGNITION; PI-STACKING; MACROCYCLES; DIMERS;
D O I：
10.1016/j.tetlet.2016.07.086
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In this study, hexagonal shape-persistent cyclophane with D-2h symmetry and rigid dihedral angles was obtained through the key SNAr reaction of perfluorobenzene moieties and dipyrroles. The X-ray analysis of the compound thus obtained revealed a hexagonal macrocyclic structure with D-2h symmetry due to the dihedral angles of 120 degrees and double 120 degrees for bicyclo[2.2.2]octadiene:fused dipyrrole and syn-diethanotetrahydroanthracene-fused dipyrrole, respectively. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4079 / 4081
页数：3
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