Photoswitching tetranuclear rhenium(I) tricarbonyl diimine complexes with a stilbene-like bridging ligand

被引：39

作者：

Lin, Ju-Ling ^{[1
]}

Chen, Chih-Wei ^{[1
]}

Sun, Shih-Sheng ^{[1
]}

Lees, Alistair J. ^{[2
]}

机构：

[1] Acad Sinica, Inst Chem, Taipei 115, Taiwan

[2] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 21期

关键词：

ENERGY-TRANSFER; PHOTOPHYSICAL PROPERTIES; SUPRAMOLECULAR SYSTEMS; CIS ISOMERIZATION; PHOTOCHEMISTRY; LUMINESCENCE; PHOTOISOMERIZATION; MECHANISMS;

D O I：

10.1039/c1cc11272d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly efficient photoswitching tetranuclear rhenium(I) tricarbonyl diimine complexes with a stilbene-like bridging ligand are reported. The ability to directly populate excited states localized on the bridging ligand is the key for the observed efficient photoisomerization.

引用

页码：6030 / 6032

页数：3

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