Cobalt-catalyzed intermolecular C-H amination with bromamine-T as nitrene source

被引：91

作者：

Harden, Jeremiah D.

Ruppel, Joshua V.

Gao, Guang-Yao

Zhang, X. Peter ^{[1
]}

机构：

[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

[2] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 44期

关键词：

D O I：

10.1039/b710677g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cobalt, supported by porphyrin ligands, is capable of catalyzing intermolecular nitrene insertion of sp(3) C-H bonds with bromamine-T as the nitrene source, forming the desired tosyl-protected amines with NaBr as the by-product.

引用

页码：4644 / 4646

页数：3

共 41 条

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