Solvent-Free Acetylation of Thiols Under Catalysis of MgBr2•OEt2

被引:2
|
作者
Mojtahedi, Mohammad M. [1 ]
Abaee, M. Saeed [1 ]
Javadpour, Mashal [1 ]
机构
[1] Chem & Chem Engn Res Ctr Iran, Tehran, Iran
关键词
Acylation; catalysis; magnesium bromide ethyl etherate; solvent-free reaction; thiol esters; DIRECT ALDOL ADDITION; SELECTIVE ACETYLATION; EFFICIENT CATALYST; VERSATILE REAGENT; SIMPLE THIOESTERS; ROOM-TEMPERATURE; MILD CONDITIONS; ACYLATION; AMINES; THIOLESTERS;
D O I
10.1080/10426501003645878
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Solvent-free protection of aromatic and aliphatic thiols with acetic anhydride was performed at room temperature under trace quantities of magnesium bromide ethyl etherate, affording rapid formation of various thiol esters in excellent yields.
引用
收藏
页码:2362 / 2365
页数:4
相关论文
共 50 条
  • [1] Efficient solvent-free aminolysis of epoxides and oxetanes under MgBr2•OEt2 catalysis
    Mojtahedi, Mohammad M.
    Abaee, M. Saeed
    Hamidi, Vahid
    CATALYSIS COMMUNICATIONS, 2007, 8 (11) : 1671 - 1674
  • [2] MgBr2•OEt2 mediated protection of alcohols with hexamethyldisilazane:: An efficient catalytic route for the preparation of silyl ethers under solvent-free conditions
    Mojtahedi, MM
    Abbasi, H
    Abaee, MS
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 250 (1-2) : 6 - 8
  • [3] MgBr2•OEt2 -: A versatile reagent in organic synthesis
    Tipparaju, SK
    SYNLETT, 2004, (05) : 912 - 913
  • [4] Efficient MgBr2•OEt2 -: catalyzed Knoevenagel condensation
    Abaee, M. Saeed
    Mojtahedi, Mohammad M.
    Zahedi, M. Mehdi
    Khanalizadeh, Golriz
    ARKIVOC, 2006, : 48 - 52
  • [5] Facile room-temperature MgBr2•OEt2-catalyzed thiolysis of epoxides under solvent-free conditions
    Mojtahedi, Mohammad M.
    Abaee, M. Saeed
    Bolourtchian, Mohammad
    Abbasi, Hassan
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2007, 182 (04) : 905 - 910
  • [6] Preparation of α-bromo-β-hydroxy esters using MgBr2•OEt2
    Lieberman, Brandin
    Cohen, Adi
    Schechter, Aaron
    Lim, Daniel
    TETRAHEDRON LETTERS, 2015, 56 (41) : 5508 - 5511
  • [7] An unexpected structural principle for crystalline MgBr2· OEt2: Chains of trigonal bipyramids
    Institut für Anorganische Chemie, Universität Karlsruhe, Engesserstr. Geb. 30.45, D-76128 Karlsruhe, Germany
    Chem. Eur. J., 9 (1112-1114):
  • [8] N-acylation of amides with acid anhydrides by way of dual activation using MgBr2•OEt2
    Yamada, S
    Yaguchi, S
    Matsuda, K
    TETRAHEDRON LETTERS, 2002, 43 (04) : 647 - 651
  • [9] MgBr2 • OEt2: A LEWIS ACID CATALYST FOR THE O- AND N-Boc PROTECTION OF PHENOLS AND AMINES
    Schechter, Aaron
    Goldrich, David
    Chapman, Jessica R.
    Uberheide, Beatrix M.
    Lim, Daniel
    SYNTHETIC COMMUNICATIONS, 2015, 45 (05) : 653 - 660
  • [10] BF3•OEt2 promoted solvent-free synthesis of benzimidazole derivatives
    Nagawade, RR
    Shinde, DB
    CHINESE CHEMICAL LETTERS, 2006, 17 (04) : 453 - 456