Direct phosphorylation of benzylic C-H bonds under transition metal-free conditions forming sp3C-P bonds

被引：6
作者：
Li, Qiang [1 ]
Zhao, Chang-Qiu [1 ]
Chen, Tieqiao [2 ]
Han, Li-Biao [2 ,3 ]
机构：
[1] Liaocheng Univ, Coll Chem & Chem Engn, 1 Hunan Rd, Liaocheng 252059, Shandong, Peoples R China
[2] Hainan Univ, Key Lab Minist Educ Adv Mat Trop Isl Resources, Hainan Prov Key Lab Fine Chem, Hainan Prov Fine Chem Engn Res Ctr, Haikou 570228, Hainan, Peoples R China
[3] Zhejiang Yanfan New Mat Co Ltd, Shangyu 312369, Zhejiang, Peoples R China
来源：
RSC ADVANCES | 2022年 / 12卷 / 29期
关键词：
DEHYDROGENATIVE-COUPLING REACTIONS; RADICAL TANDEM CYCLIZATION; REGIOSELECTIVE PHOSPHONATION; ARYLBORONIC ACIDS; CATALYTIC AMOUNTS; EFFICIENT; FUNCTIONALIZATION; ACTIVATION; VERSATILE; AMINES;
D O I：
10.1039/d2ra02812c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Direct phosphorylation of benzylic C-H bonds was achieved in a biphasic system under transition metal-free conditions. A selective radical/radical sp(3)C-H/P(O)-H cross coupling was proposed, and various substituted toluenes were applicable. The transformation provided a promising method for constructing sp(3)C-P bonds.
引用
收藏
页码：18441 / 18444
页数：4
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