Lysine-assisted hydrothermal synthesis of urchin-like ordered arrays of mesoporous Co(OH)2 nanowires and their application in electrochemical capacitors

被引:112
作者
Yuan, Changzhou [1 ]
Zhang, Xiaogang [2 ]
Hou, Linrui [1 ]
Shen, Laifa [2 ]
Li, Diankai [1 ]
Zhang, Fang [2 ]
Fan, Chuangang [1 ]
Li, Jiamao [1 ]
机构
[1] Anhui Univ Technol, Sch Mat Sci & Engn, Maanshan 243002, Peoples R China
[2] Nanjing Univ Aeronaut & Astronaut, Coll Mat Sci & Engn, Nanjing 210016, Peoples R China
基金
中国国家自然科学基金;
关键词
ENERGY-CONVERSION; STORAGE; NANOSTRUCTURES; TEMPERATURE; CARBON; CO3O4; SUPERCAPACITORS; NANOPARTICLES; PERFORMANCE; MORPHOLOGY;
D O I
10.1039/c0jm02174a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the work, a novel lysine-assisted hydrothermal process is first developed to produce urchin-like ordered Co(OH)(2) arrays, which are assembled from mesoporous Co(OH)(2) nanowires. The synergistic contributions from lysine and Cl- ions to the formation of the unique arrays was also tentatively proposed. Electrochemical results show that the unique urchin-like ordered Co(OH)(2) arrays show the ability to deliver large specific capacitance and good electrochemical stability at large current densities, which is reasonably ascribed to their ordered microstructure, hierarchical (meso-and macro-) porosity and good electronic conductivity. Moreover, the method we proposed here provides a universal green chemistry approach to large-scale production of Co(OH)(2) and even other metal hydroxides oriented arrays with hierarchical porosity for fast energy storage.
引用
收藏
页码:10809 / 10816
页数:8
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