Lysine-assisted hydrothermal synthesis of urchin-like ordered arrays of mesoporous Co(OH)2 nanowires and their application in electrochemical capacitors
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作者:
Yuan, Changzhou
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Anhui Univ Technol, Sch Mat Sci & Engn, Maanshan 243002, Peoples R ChinaAnhui Univ Technol, Sch Mat Sci & Engn, Maanshan 243002, Peoples R China
Yuan, Changzhou
[1
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Zhang, Xiaogang
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Nanjing Univ Aeronaut & Astronaut, Coll Mat Sci & Engn, Nanjing 210016, Peoples R ChinaAnhui Univ Technol, Sch Mat Sci & Engn, Maanshan 243002, Peoples R China
Zhang, Xiaogang
[2
]
Hou, Linrui
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Anhui Univ Technol, Sch Mat Sci & Engn, Maanshan 243002, Peoples R ChinaAnhui Univ Technol, Sch Mat Sci & Engn, Maanshan 243002, Peoples R China
Hou, Linrui
[1
]
Shen, Laifa
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Nanjing Univ Aeronaut & Astronaut, Coll Mat Sci & Engn, Nanjing 210016, Peoples R ChinaAnhui Univ Technol, Sch Mat Sci & Engn, Maanshan 243002, Peoples R China
Shen, Laifa
[2
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Li, Diankai
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Anhui Univ Technol, Sch Mat Sci & Engn, Maanshan 243002, Peoples R ChinaAnhui Univ Technol, Sch Mat Sci & Engn, Maanshan 243002, Peoples R China
Li, Diankai
[1
]
Zhang, Fang
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Nanjing Univ Aeronaut & Astronaut, Coll Mat Sci & Engn, Nanjing 210016, Peoples R ChinaAnhui Univ Technol, Sch Mat Sci & Engn, Maanshan 243002, Peoples R China
Zhang, Fang
[2
]
Fan, Chuangang
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Anhui Univ Technol, Sch Mat Sci & Engn, Maanshan 243002, Peoples R ChinaAnhui Univ Technol, Sch Mat Sci & Engn, Maanshan 243002, Peoples R China
Fan, Chuangang
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Li, Jiamao
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Anhui Univ Technol, Sch Mat Sci & Engn, Maanshan 243002, Peoples R ChinaAnhui Univ Technol, Sch Mat Sci & Engn, Maanshan 243002, Peoples R China
Li, Jiamao
[1
]
机构:
[1] Anhui Univ Technol, Sch Mat Sci & Engn, Maanshan 243002, Peoples R China
[2] Nanjing Univ Aeronaut & Astronaut, Coll Mat Sci & Engn, Nanjing 210016, Peoples R China
In the work, a novel lysine-assisted hydrothermal process is first developed to produce urchin-like ordered Co(OH)(2) arrays, which are assembled from mesoporous Co(OH)(2) nanowires. The synergistic contributions from lysine and Cl- ions to the formation of the unique arrays was also tentatively proposed. Electrochemical results show that the unique urchin-like ordered Co(OH)(2) arrays show the ability to deliver large specific capacitance and good electrochemical stability at large current densities, which is reasonably ascribed to their ordered microstructure, hierarchical (meso-and macro-) porosity and good electronic conductivity. Moreover, the method we proposed here provides a universal green chemistry approach to large-scale production of Co(OH)(2) and even other metal hydroxides oriented arrays with hierarchical porosity for fast energy storage.