Study on the modification of inclusions by Ca treatment in GCr18Mo bearing steel

被引:17
作者
Zheng, Hong-Yan [1 ,2 ,3 ]
Guo, Shu-Qiang [1 ,2 ,3 ]
Qiao, Meng-Ran [1 ,2 ,3 ]
Qin, Li-Bin [1 ,2 ,3 ]
Zou, Xiu-Jing [1 ,2 ,3 ]
Ren, Zhong-Ming [1 ,2 ,3 ]
机构
[1] Shanghai Univ, State Key Lab Adv Special Steel, Shanghai 200444, Peoples R China
[2] Shanghai Univ, Shanghai Key Lab Adv Ferromet, Shanghai 200444, Peoples R China
[3] Shanghai Univ, Sch Mat Sci & Engn, Shanghai 200444, Peoples R China
基金
中国国家自然科学基金;
关键词
GCr18Mo bearing steel; Ca treatment; Inclusion modification; Deoxidization; Thermodynamics; CALCIUM; DEOXIDATION; EQUILIBRIUM; ALUMINUM; IRON;
D O I
10.1007/s40436-019-00266-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The effect of Ca treatment on the modification of inclusions in Al-killed GCr18Mo bearing steel was studied and a thermodynamic and kinetic model was established. The experimental results showed that oxygen content in the steel could be reduced from 120 mu g/g to the range 5.5-21.6 mu g/g by Al-Ca complex deoxidization at 1 873 K. An appropriate increase in Ca/Al mass ratio is beneficial to reduce the total oxygen content in steel. When the content of dissolved aluminum was in the range of 0.03%-0.3%, with the increase of Ca/Al mass ratio from 0.8-1.6 to 2.4-3.2, the number of inclusions per unit area significantly reduced. In addition, the main types of inclusions were modified from large-sized Al2O3 clusters to plastic or semi-plastic liquid phase calcium aluminates. The experimental results matched well with the thermodynamic analysis.
引用
收藏
页码:438 / 447
页数:10
相关论文
共 21 条
[1]   Study of Inclusions in High Sulfur, Al-Killed Ca-Treated Steel via Experiments and Thermodynamic Calculations [J].
Bielefeldt, Wagner Viana ;
Faria Vilela, Antonio Cezar .
STEEL RESEARCH INTERNATIONAL, 2015, 86 (04) :375-385
[2]   Development of an integrated method for fully characterizing multiphase inclusions and its application to calcium-treated steels [J].
Blais, C ;
LEsperance, G ;
Lehuy, H ;
Forget, C .
MATERIALS CHARACTERIZATION, 1997, 38 (01) :25-37
[3]  
Chen J., 2010, COMMONLY USED CHART
[4]   ASSESSMENT OF THE CAO-AL2O3 SYSTEM [J].
HALLSTEDT, B .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1990, 73 (01) :15-23
[5]   On Physico-Chemical and Technical Limits in Clean Steel Production [J].
Holappa, L. .
STEEL RESEARCH INTERNATIONAL, 2010, 81 (10) :869-874
[6]  
Huang, 1981, PRINCIPLES IRON STEE
[7]   Deoxidation equilibrium of calcium in liquid iron [J].
Itoh, H ;
Hino, M ;
BanYa, S .
TETSU TO HAGANE-JOURNAL OF THE IRON AND STEEL INSTITUTE OF JAPAN, 1997, 83 (11) :695-700
[8]   Effect of Mg and Ca Treatment on Behavior and Particle Size of Inclusions in Bearing Steels [J].
Ma, Wenjun ;
Bao, Yanping ;
Wang, Min ;
Zhao, Lihua .
ISIJ INTERNATIONAL, 2014, 54 (03) :536-542
[9]  
Murray JD, 1963, J IRON STEEL I, V86, P375
[10]  
Ning M, 2005, CSM 2005 ANN M P, P246