Experimental and theoretical studies of the Si(100)/SiO2 interface formed by wet and dry oxidation

被引:0
作者
Chowdhuri, AR [1 ]
Jin, DU [1 ]
Takoudis, CG [1 ]
机构
[1] Univ Illinois, Dept Chem Engn, Chicago, IL 60607 USA
来源
CRYSTALLINE OXIDE-SILICON HETEROSTRUCTURES AND OXIDE OPTOELECTRONICS | 2003年 / 747卷
关键词
D O I
暂无
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Interfacial strain and substoichiometric silicon oxides are the two principal causes that result in the redshift of the transverse and longitudinal optical phonons of the asymmetric stretch of O in the Si-O-Si bridging bond of thermal SiO(2) with decreasing oxide thickness. Analyses to comprehend these effects, therefore, require consideration of both strain and interfacial substoichiometry. A method to isolate the contributions of strain and suboxide content towards the observed shifts is proposed. The procedure, which utilizes simple optical model and effective medium approximation, allows estimation of the average strain and suboxide concentration in films of different thickness. Analyses of oxides formed at two different temperatures (550 and 700degreesC) with dry and wet oxygen reveal how process conditions affect the interface properties.
引用
收藏
页码:329 / 334
页数:6
相关论文
共 50 条
[21]   Generation of excess Si species at Si/SiO2 interface and their diffusion into SiO2 during Si thermal oxidation [J].
Ibano, Kenzo ;
Itoh, Kohei M. ;
Uematsua, Masashi .
JOURNAL OF APPLIED PHYSICS, 2008, 103 (02)
[22]   Molecular dynamics study of Si(100)-oxidation: SiO and Si emissions from Si/SiO2 interfaces and their incorporation into SiO2 [J].
Takahashi, Norihiko ;
Yamasaki, Takahiro ;
Kaneta, Chioko .
JOURNAL OF APPLIED PHYSICS, 2014, 115 (22)
[23]   Discrete Electron States at the Si(100)/SiO2 Interface [J].
Kirillova S.I. ;
Primachenko V.E. ;
Serba A.A. ;
Chernobai V.A. .
Russian Microelectronics, 2000, 29 (5) :345-348
[24]   Treatment of electrostatic interactions at the Si(100)-SiO2 interface [J].
Prosandeyev, SA ;
Boureau, G ;
Carniato, S .
COMPUTATIONAL MATERIALS SCIENCE, 1998, 10 (1-4) :159-162
[25]   Modelling oxygen vacancies at the Si(100)-SiO2 interface [J].
Carniato, S ;
Boureau, G ;
Harding, JH .
PHILOSOPHICAL MAGAZINE A-PHYSICS OF CONDENSED MATTER STRUCTURE DEFECTS AND MECHANICAL PROPERTIES, 1997, 75 (05) :1435-1445
[26]   PROCESS DEPENDENCE OF THE SIO2/SI(100) INTERFACE STRUCTURE [J].
LU, ZH ;
TAY, SP ;
MILLER, T ;
CHIANG, TC .
JOURNAL OF APPLIED PHYSICS, 1995, 77 (08) :4110-4112
[27]   SiO2 formation at the aluminum Oxide/Si(100) interface [J].
Chowdhuri, AR ;
Takoudis, CG ;
Klie, RF ;
Browning, ND .
CRYSTALLINE OXIDE-SILICON HETEROSTRUCTURES AND OXIDE OPTOELECTRONICS, 2003, 747 :335-340
[28]   Reaction mechanisms of oxygen at SiO2/Si(100) interface [J].
Akiyama, T ;
Kageshima, H .
SURFACE SCIENCE, 2005, 576 (1-3) :L65-L70
[29]   Structure and electronic property of Si(100)/SiO2 interface [J].
Kaneta, C ;
Yamasaki, T ;
Uchiyama, T ;
Uda, T ;
Terakura, K .
MICROELECTRONIC ENGINEERING, 1999, 48 (1-4) :117-120
[30]   SURFACE-ROUGHNESS AT THE SI(100)-SIO2 INTERFACE [J].
GOODNICK, SM ;
FERRY, DK ;
WILMSEN, CW ;
LILIENTAL, Z ;
FATHY, D ;
KRIVANEK, OL .
PHYSICAL REVIEW B, 1985, 32 (12) :8171-8186