High sensitivity cavity ring down spectroscopy of the ν1 + ν43 band of NO2 near 1.34 μm

被引：7

作者：

Lukashevskaya, A. A. ^{[1
]}

Mondelain, D. ^{[2
]}

Campargue, A. ^{[2
]}

Perevalov, V. I. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, VE Zuev Inst Atmospher Opt, Lab Theoret Spect, 1 Academician Zuev Sq, Tomsk 634055, Russia

[2] Univ Grenoble Alpes, CNRS, LIPhy, F-38000 Grenoble, France

来源：

JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER | 2018年 / 219卷

基金：

俄罗斯科学基金会;

关键词：

Nitrogen dioxide; NO2; High resolution spectroscopy; Cavity ring down spectroscopy; Electron spin-rotation interaction; Effective Hamiltonian; HIGH-RESOLUTION ANALYSIS; NITROGEN-DIOXIDE; NO2; BAND; EDITION; LINES;

D O I：

10.1016/j.jqsrt.2018.07.021

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

The very weak nu(1)+4 nu(3) B-type absorption band of nitrogen dioxide ((NO2)-N-14-O-16) is newly detected by high sensitivity continuous wave-cavity ring clown spectroscopy between 7376 and 7550 cm(-1). The noise equivalent absorption of the recordings is alpha(min) approximate to 1 x 10(-10) cm(-1). The nu(1)+4 nu(3) band is the highest energy B-type absorption band of NO2 detected so far by absorption within the ground electronic state. More than 800 lines are assigned with rotational quantum numbers N and K-alpha up to 50 and 7, respectively, what corresponds to 1117 spin-rotation-vibration transitions. No resonance perturbation of the spectrum was observed. The fitted set of the effective Hamiltonian parameters reproduces the observed line positions with an rms of 3.7 x 10(-3) cm(-1). A selected set of measured line intensities are used to determine the effective dipole moment parameters including two Herman-Wallis type parameters. The rms deviation of the intensity fit is 15.2%. (C) 2018 Elsevier Ltd. All rights reserved.

引用

页码：393 / 398

页数：6

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