Graphene-wrapped ZnO nanospheres as a photocatalyst for high performance photocatalysis

被引:61
作者
Chen, Da [1 ]
Wang, Dongfang [1 ]
Ge, Qisheng [1 ]
Ping, Guangxing [1 ]
Fan, Meiqiang [1 ]
Qin, Laishun [1 ]
Bai, Liqun [2 ]
Lv, Chunju [1 ]
Shu, Kangying [1 ]
机构
[1] China Jiliang Univ, Coll Mat Sci & Engn, Hangzhou 310018, Zhejiang, Peoples R China
[2] Zhejiang Agr & Forestry Univ, Sch Sci, Hangzhou 311300, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
Graphene; Zinc Oxide; Nanospheres; Lyophilization; Photocatalytic activity; GRAPHITE OXIDE; VISIBLE-LIGHT; NANOCOMPOSITES; SHEETS; FILMS; NANOCRYSTALS; DEGRADATION; REDUCTION; COMPOSITE; DYES;
D O I
10.1016/j.tsf.2014.11.051
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this work, graphene-wrapped ZnO nanospheres (ZnO-graphene nanocomposites) were prepared by a simple facile lyophilization method, followed by thermal treatment process. ZnO nanospheres with the size of about 100-400 nm, composed of numerous nanocrystals with hexagonal wurtzite structure, were well separated from each other and wrapped with transparent graphene sheets. Compared to ZnO nanospheres, the ZnO-graphene nanocomposites showed a significant enhancement in the photodegradation of methylene blue. This enhanced photocatalytic activity could be attributed to their favorable dye-adsorption affinity and increased optical absorption as well as the efficient charge transfer of the photogenerated electrons in the conduction band of ZnO to graphene. Thus, this work could provide a facile and low-cost method for the development of graphene-based nanocomposites with promising applications in photocatalysis, solar energy conversion, sensing, and so on. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 9
页数:9
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