Innovative integrated process for the treatment of azo dyes: coupling of photocatalysis and biological treatment

被引:39
作者
Brosillon, S. [1 ]
Djelal, H. [1 ]
Merienne, N. [1 ]
Amrane, A. [1 ]
机构
[1] Univ Rennes 1, Ecole Natl Super Chim Rennes, Equipe Chim & Ingn Procedes, CNRS SCR UMR 6226, F-35700 Rennes, France
关键词
azo dyes; biodegradation; integrated processes; photocatalysis;
D O I
10.1016/j.desal.2007.01.153
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Tests of the biodegradation of the azo dyes Reactive Black 5 and Reactive Yellow 145 confirmed the low biodegradability of these components in the considered conditions, namely a strain of Pseudomonas fluorescens, cultivated at 25 degrees C, an initial pH of 7 and in presence of a supplementary carbon source, glucose. Indeed, for an initial dye concentration of 40 ppm, the maximum yields of decolouration were 27% and 18% for the two dyes RB5 and RY145. Some tests of biological mineralisation of solutions preliminary photocatalysed demonstrate a mineralisation of the considered solutions for various irradiation times. Identification of the intermediate by-products is in progress to propose a reaction pathway.
引用
收藏
页码:331 / 339
页数:9
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