Convenient synthesis of deuterium labelled sesquiterpenes

被引：10

作者：

Duhamel, Nina ^{[1
]}

Martin, Damian ^{[2
]}

Larcher, Roberto ^{[3
]}

Fedrizzi, Bruno ^{[1
]}

Barker, David ^{[1
]}

机构：

[1] Univ Auckland, Sch Chem Sci, 23 Symonds St, Auckland, New Zealand

[2] New Zealand Inst Plant & Food Res Ltd, 85 Budge St, Marlborough 7240, New Zealand

[3] FEM IASMA Fdn Edmund Mach, Ist Agr San Michele Alladige, Via E Mach 1, I-38010 San Michele All Adige, TN, Italy

来源：

TETRAHEDRON LETTERS | 2016年 / 57卷 / 40期

关键词：

Sesquiterpenes; Isotopic labelling; Deuterium; Terpenoids; BAR SORPTIVE EXTRACTION; NATURAL SESQUITERPENOIDS; LIQUID DESORPTION; L; (+)-AROMADENDRENE; REARRANGEMENT; BIOSYNTHESIS; PROTEOMICS; VARIETIES; VOLATILES;

D O I：

10.1016/j.tetlet.2016.08.079

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sesquiterpenes are an important class of molecules, with roles ranging from pollination and signalling to defense mechanisms. Despite their apparent importance, the limited number of commercial standards has hindered their study and precise quantification. Herein, we report the syntheses of fourteen labelled sesquiterpenes with a high level of deuterium incorporation (>95%) for applications in MS-based studies. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：4496 / 4499

页数：4

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