New avenues in dinitrogen fixation research

被引：2

作者：

Hoshino, K ^{[1
]}

机构：

[1] Chiba Univ, Fac Engn, Inage Ku, Chiba 2638522, Japan

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2001年 / 7卷 / 13期

关键词：

conducting materials; nitrogen fixation; semiconductors; solid-state reactions; titanium oxide;

D O I：

10.1002/1521-3765(20010702)7:13<2727::AID-CHEM2727>3.0.CO;2-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The present article focuses on a recent finding concerning dinitrogen fixation by using titanium oxide/conducting polymer composite systems and its comparison with an earlier fixation method (Schrauzer process) that makes use of a powdered titanium oxide. Both processes work under the stimulus of light at room temperature and pressure, but dinitrogen is fixed to a solid ammonium salt crystal in the former and to a gaseous ammonia molecule in the latter process. Differences in the physicochemical concepts between the two processes are discussed.

引用

页码：2727 / 2731

页数：5

共 56 条

[1] NITROGENOPENTAMMINERUTHENIUM(2) COMPLEXES [J].