Electrochemical synthesis of a copolymer of poly(3-octylthiophene) and poly(paraphenylene)

被引：34

作者：

Latonen, RM ^{[1
]}

Kvarnström, C ^{[1
]}

Ivaska, A ^{[1
]}

机构：

[1] Abo Akad Univ, Analyt Chem Lab, FIN-20500 Turku, Finland

来源：

ELECTROCHIMICA ACTA | 1999年 / 44卷 / 12期

关键词：

D O I：

10.1016/S0013-4686(98)00302-8

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Electrochemical copolymerization of 3-octylthiophene and biphenyl and the redox behaviour of the formed copolymer films have been Studied. Influence of different polymerization parameters such as the concentrations and the ratios of the starting materials and the current density on the formed copolymer material was studied. Synthesis of the copolymer films was studied and verified by cyclic voltammetric experiments, FT-IR measurements, scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDXA). The content of each of the monomer units in the copolymer films was found to be highly dependent on both the ratio and concentration of the starting materials and the current density used. The structure of the copolymer depends also on the thickness of the film. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：1933 / 1943

页数：11

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