X-ray study of two ZnII and CdII 2,2′-dipyridylamine thiosulfate compounds

被引：10

作者：

Freire, E

Baggio, S

Mombrú, A

Baggio, R

机构：

[1] Comis Nacl Energia Atom, Dept Fis, RA-1429 Buenos Aires, DF, Argentina

[2] Univ Nacl Patagonia, Sede Puerto Madryn, RA-9120 Puerto Madryn, Chubut, Argentina

[3] Consejo Nacl Invest Cient & Tecn, CenPat, RA-9120 Puerto Madryn, Chubut, Argentina

[4] Univ Republica, Fac Quim, Lab Cristalog & Quim Estado Solido, Montevideo, Uruguay

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2001年 / 54卷 / 03期

关键词：

D O I：

10.1071/CH01029

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two Zn-II and Cd-II thiosulfato(2,2'-dipyridylamine) complexes, namely [Zn-2(S2O3)(2)(dpa)(3).H2O].H2O (1) and [Cd(S2O3)(dpa)(H2O)] (2) (dpa = 2,2'-dipyridylamine), have been prepared and their crystal structures determined and compared with related structures in the literature. Compound (1) is triclinic P (1) over bar, a 10.170(3), b 12.821(3), c 14.899(3) Angstrom, alpha 108.33(2), beta 90.34(2), gamma 109.02( 2)degrees, V 1730.7( 7) Angstrom (3), Z 2, conventional R (on F) being 0.031 for 6379 N-o observed reflections (I>2 sigma (I)). Compound (2) is monoclinic, P2(1)/c, a 9.897( 3), b 19.235(4), c 7.205( 1) Angstrom, beta 101.48(7)degrees, V 1344.2(4) Angstrom (3), Z 4, R 0.032, N-o 2494.

引用

页码：193 / 197

页数：5

共 13 条

[1] ALLEN FH, 1993, CHEM DESIGN AUTOMATI, V8, P1
[2] Cis-diaquabis(1,10-phenanthroline-N,N')zinc(II) (1,10-phenanthroline-N,N')bis(thiosulfato-S)zincate(II) monohydrate
Baggio, R
Baggio, S
Pardo, MI
Garland, MT
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1996, 52 : 820 - 823
[3] Bis(mu-thiosulfato)-1 kappa O,1:2 kappa S-2;2 kappa O,1:2 kappa S-2-bis[(2,9-dimethyl-1,10-phenanthroline-N,N')cadmium(II)]
Baggio, R
Baggio, S
Pardo, MI
Garland, MT
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 (pt 8) : 1939 - 1942
[4] Sodium bis(2,9-dimethyl-1,10-phenanthroline)-mu-hydroxo-di(thiosulfato)dizinc(II) pentahydrate methanol solvate
Baggio, S
Pardo, MI
Baggio, R
Garland, MT
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 551 - 554
[5] Tris(2,2'-bipyridyl-N,N')zinc(II) thiosulfate heptahydrate
Baggio, S
Pardo, MI
Baggio, R
Garland, MT
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 1570 - 1572
[6] Aqua(1,10-phenanthroline-N,N′)(μ3-thiosulfato-S:S:O)cadmium(II) hydrate
Baggio, S
Baggio, R
Garland, MT
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 : 1099 - 1102
[7] (2,2'-bipyridine-N,N')(mu-thiosulfato)-cadmium(II)
Baggio, S
Pardo, MI
Baggio, R
Garland, MT
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 727 - 729
[8] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE
BROWN, ID
ALTERMATT, D
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG): : 244 - 247
[9] VIBRATIONAL SPECTRA AND STRUCTURES OF SOME THIOSULPHATE COMPLEXES
FREEDMAN, AN
STRAUGHAN, BP
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1971, A 27 (08): : 1455 - +
[10] *JCPDS INT CTR DIF, 1992, 361451 JCPDS INT CTR

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