A Swiss-roll liquid-gas mixed-reactant fuel cell

被引:25
作者
Aziznia, Amin [1 ,2 ]
Oloman, Colin W. [1 ,2 ]
Gyenge, Elod L. [1 ,2 ]
机构
[1] Univ British Columbia, Dept Chem & Biol Engn, Vancouver, BC V6T 1Z3, Canada
[2] Univ British Columbia, CERC, Vancouver, BC V6T 1Z3, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
Mixed reactant fuel cells; Direct borohydride fuel cells; Alkaline fuel cells; Electrochemical reactors; OXYGEN REDUCTION; BOROHYDRIDE OXIDATION; OPERATION CONDITIONS; SODIUM-BOROHYDRIDE; CATHODE CATALYSTS; PERFORMANCE; ANODE; ELECTROCATALYSTS; ELECTROLYTE; MEMBRANE;
D O I
10.1016/j.jpowsour.2012.03.047
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Fuel cells face challenges related to performance and cost that stem in part from constraints of the conventional plate-and-frame architecture in vogue since Volta's time. Here, we present for the first time a cylindrical Swiss-roll mixed-reactant fuel cell (SR-MRFC) that addresses some of these challenges by eliminating ion exchange membranes and flow-field plates, to provide a light, compact multi-cell stack. We demonstrate the monopolar and bipolar SR-MRFC for the borohydride-oxygen system, using a liquid/gas mixture of 1 M NaBH4/2 M NaOH and O-2. A 3D anode with Pt/C (or PtRu/C) on carbon cloth was coupled with a gas-diffusion Ag/C (or MnO2/C) cathode. At 323 K and atmospheric pressure, a peak power density of density of 1000 W m(-2) was achieved with good performance stability. The reactor concept presented here is applicable to a variety of alkaline or acid fuel cell systems. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:154 / 160
页数:7
相关论文
共 48 条
[1]   Evaluation of colloidal Ag and Ag-alloys as anode electrocatalysts for direct borohydride fuel cells [J].
Atwan, Mohammed H. ;
Northwood, Derek O. ;
Gyenge, Elod L. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2007, 32 (15) :3116-3125
[2]   Mixed-reactant, strip-cell direct methanol fuel cells [J].
Barton, SC ;
Patterson, T ;
Wang, E ;
Fuller, TF ;
West, AC .
JOURNAL OF POWER SOURCES, 2001, 96 (02) :329-336
[3]   Review of materials and characterization methods for polymer electrolyte fuel cell flow-field plates [J].
Brett, Daniel J. L. ;
Brandon, Nigel P. .
JOURNAL OF FUEL CELL SCIENCE AND TECHNOLOGY, 2007, 4 (01) :29-44
[4]   Effects of operation conditions on direct borohydride fuel cell performance [J].
Celik, Cenk ;
San, Fatma Gul Boyaci ;
Sarac, Halil Ibrahim .
JOURNAL OF POWER SOURCES, 2008, 185 (01) :197-201
[5]   Kinetics of sodium borohydride direct oxidation and oxygen reduction in sodium hydroxide electrolyte -: Part II.: O2 reduction [J].
Chatenet, Marian ;
Micoud, Fabrice ;
Roche, Ivan ;
Chainet, Eric ;
Vondrak, Jiri .
ELECTROCHIMICA ACTA, 2006, 51 (25) :5452-5458
[6]   Investigation of Ti mesh-supported anodes for direct borohydride fuel cells [J].
Cheng, H. ;
Scott, K. .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2006, 36 (12) :1361-1366
[7]   Material aspects of the design and operation of direct borohydride fuel cells [J].
Cheng, H. ;
Scott, K. ;
Lovell, K. .
FUEL CELLS, 2006, 6 (05) :367-375
[8]   Investigation of non-platinum cathode catalysts for direct borohydride fuel cells [J].
Cheng, H. ;
Scott, K. .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2006, 596 (02) :117-123
[9]   Influence of operation conditions on direct borohydride fuel cell performance [J].
Cheng, H. ;
Scott, K. .
JOURNAL OF POWER SOURCES, 2006, 160 (01) :407-412
[10]   Physicochemical properties of alkaline aqueous sodium metaborate solutions [J].
Cloutier, Caroline R. ;
Alfantazi, Akram ;
Gyenge, Elod .
JOURNAL OF FUEL CELL SCIENCE AND TECHNOLOGY, 2007, 4 (01) :88-98