Effects of biological treatment on the chemical structure of dissolved lignin-related substances in effluent from thermomechanical pulping

被引:16
作者
Andersson, Kerstin I. [1 ,2 ]
Pranovich, Andrey V. [3 ]
Norgren, Magnus [1 ]
Eriksson, Marie [2 ]
Holmbom, Bjarne [3 ]
机构
[1] Mid Sweden Univ, FSCN, SE-85170 Sundsvall, Sweden
[2] SCA R&D Ctr, SE-85121 Sundsvall, Sweden
[3] Abo Akad Univ, Proc Chem Ctr, Lab Wood & Paper Chem, FI-20500 Turku, Finland
关键词
wastewater treatment; biodegradability; thermomechanical pulping; lignin; COD; chromatography; spectrometry;
D O I
10.3183/npprj-2008-23-02-p164-171
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
Effluent from a TMP-based pulp and paper mill was collected at the inlet and outlet of the mill's biological treatment plant and fractionated by sorption on XAD-8 resin and MTBE precipitation. Fractionation indicated that the refractory dissolved organic material in biologically treated effluent was mainly composed of lignin-related substances. Characterisation of the lignin-related substances by chromatographic and spectrometric methods confirmed the similarities of the isolated material and milled wood lignin. Fractionation and characterisation of alkali-extracted material from solids (biosludge) in biologically treated effluent found evidence of lignin-related material. Results indicated that biological treatment had altered the chemical structure and molar-mass distribution of dissolved lignin-related substances.
引用
收藏
页码:164 / 171
页数:8
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