Synthesis and evaluation of Naphthalene-1, 8-dithiolate chelating ruthenium carbene catalyst for Z-Stereoretentive olefin metathesis

被引：5

作者：

Wang, Tao ^{[1
,2
]}

Xie, Qingxiao ^{[1
,2
]}

Guo, Weijie ^{[1
,2
]}

Wu, Shutao ^{[1
,2
]}

Zhang, Huiqing ^{[1
,2
]}

Wang, Jianhui ^{[1
,2
]}

机构：

[1] Tianjin Univ, Dept Chem, Coll Sci, Tianjin 300350, Peoples R China

[2] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 30072, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2019年 / 880卷

基金：

中国国家自然科学基金;

关键词：

Ruthenium carbene catalyst; Naphthalene-1,8-dithiolate chelating; Z-Stereoretentive; Cross-metathesis reactions; CLOSING ALKYNE METATHESIS; STEREOSELECTIVE-SYNTHESIS; CROSS-METATHESIS; COMPLEXES; EFFICIENT; POLYMERIZATION; MOLYBDENUM; DERIVATIVES; REACTIVITY; ALCOHOLS;

D O I：

10.1016/j.jorganchem.2018.10.035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A highly Z-stereoretentive olefin metathesis ruthenium carbene catalyst containing a naphthalene-1,8-dithiol ligand was synthesized, and the structure was determined by single-crystal X-ray diffraction. The new ruthenium carbene catalyst could catalyze cross-metathesis reactions of terminal alkenes with (Z)-but-2-ene-1,4-diol to give highly Z-stereoretentive products. Like to other ruthenium carbene catalysts, the new complex tolerates many different functional groups. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：62 / 67

页数：6

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