Study on physical and chemical characteristics of β-hemihydrate phosphogypsum

被引:25
作者
Chen, Xuemei [1 ,2 ]
Liu, Yuanzheng [3 ]
Wu, Qihong [1 ,2 ]
Ding, Yi [4 ]
Wang, Qingyuan [1 ,2 ]
Tang, Wenjie [1 ]
Zhu, Baiyu [1 ]
机构
[1] Chengdu Univ, Coll Architechture & Civil Engn, Chengdu 610106, Peoples R China
[2] Chengdu Univ, Sichuan Prov Engn Res Ctr City Solid Waste Energy, Chengdu 610106, Peoples R China
[3] Sichuan Huayizhongchuang New Mat Co LTD, Chengdu 610300, Peoples R China
[4] Anhui Jianzhu Univ, Anhui Prov Key Lab Adv Bldg Mat, Hefui 230601, Peoples R China
关键词
Hemihydrate phosphogypsum; Microstructure; Compatibility; Hydration; GYPSUM; HYDRATION; ACID;
D O I
10.1016/j.cscm.2022.e01461
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
Calcium sulfate hemihydrate is the most widely used binder for gypsum-based materials. This paper investigates the physical and chemical characteristics of beta-hemihydrate phosphogypsum aiming to promote the utilization of phosphogypsum on a large scale. A comparative study of HPG, HFG and HNG based on particle characteristics, composition analysis, hydration charac-teristics, microstructure, and compatibility with admixtures was performed. The results show that the acidic hydration environment and co-crystallized phosphate are particular for HPG. The optimal admixtures for HPG are protein retarder and polycarboxylate superplasticizer. Besides, an increase in HPG particle fineness would promote hydration and improve mechanical strength in the presence of a water reducer. The comparable strength and the same hydration mechanism support that HPG is a competitive binder with HFG and HNG. These findings are desirable for industrial application.
引用
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页数:16
相关论文
共 30 条
[21]   Chemical treatment of phosphogypsum and its potential application for building and construction [J].
Mashifana, T. P. .
2ND INTERNATIONAL CONFERENCE ON SUSTAINABLE MATERIALS PROCESSING AND MANUFACTURING (SMPM 2019), 2019, 35 :641-648
[22]  
Mullin J. W., 2001, Crystallization
[23]   Hydrogen-enriched syngas production by lignite chemical looping gasification with composite oxygen carriers of phosphogypsum and steel slag [J].
Pan, Qinghuan ;
Ma, Liping ;
Du, Wang ;
Yang, Jie ;
Ao, Ran ;
Yin, Xia ;
Qing, Sancheng .
ENERGY, 2022, 241
[24]   Phosphogypsum as a construction material [J].
Rashad, Alaa M. .
JOURNAL OF CLEANER PRODUCTION, 2017, 166 :732-743
[25]  
Scrivener K., 2016, PRACTICAL GUIDE MICR, V540, P37
[26]   Effect of phosphatic and fluoride impurities of phosphogypsum on the properties of selenite plaster [J].
Singh, M .
CEMENT AND CONCRETE RESEARCH, 2003, 33 (09) :1363-1369
[27]   Calcium sulphate hemihydrate hydration leading to gypsum crystallization [J].
Singh, N. B. ;
Middendorf, B. .
PROGRESS IN CRYSTAL GROWTH AND CHARACTERIZATION OF MATERIALS, 2007, 53 (01) :57-77
[28]   Dehydration Pathways of Gypsum and the Rehydration Mechanism of Soluble Anhydrite γ-CaSO4 [J].
Tang, Yongbo ;
Gao, Jianming ;
Liu, Chuanbei ;
Chen, Xuemei ;
Zhao, Yasong .
ACS OMEGA, 2019, 4 (04) :7636-7642
[29]   Study on the improvement of the waterproof and mechanical properties of hemihydrate phosphogypsum-based foam insulation materials [J].
Wang, Qiang ;
Cui, Yong ;
Xue, Junfeng .
CONSTRUCTION AND BUILDING MATERIALS, 2020, 230
[30]  
Yang K.R., 2005, J HEBEI I TECHNOL, V5, P88