The azaphilic addition of organometallic reagents on tetrazines:: scope and limitations

被引：24
|
作者：
Faragó, J
Novák, Z
Schlosser, G
Csámpai, A
Kotschy, A [1 ]
机构：
[1] Eotvos Lorand Univ, Dept Gen & Inorgan Chem, Pazmany Peter S 1-A, H-1117 Budapest, Hungary
[2] Hungarian Acad Sci, Chem Res Ctr, H-1525 Budapest, Hungary
来源：
TETRAHEDRON | 2004年 / 60卷 / 09期
关键词：
tetrazines; azaphilic addition; aromatic nucleophilic substitution; reduction;
D O I：
10.1016/j.tet.2004.01.013
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of tetrazines were reacted with organometallic reagents. Depending on the nature of the metal azaphilic addition, reduction of the tetrazine or simple complex formation was the predominant transformation and usually high selectivity was observed. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1991 / 1996
页数：6
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