Synthesis of one-dimensional nanostructure of chromium nitride

被引:12
作者
Cai, PJ
Zhu, J
Yang, ZH
Qian, YT [1 ]
机构
[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
[2] Xuzhou Normal Univ, Res Ctr Expt, Xuzhou 221009, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
one-dimension; nanostructure; chromium nitride; chemical synthesis;
D O I
10.1016/j.matchemphys.2005.04.032
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
One-dimensional (1D) nanostructured materials, chromium nitride (CrN) nanorods have been prepared initially via a direct thermal solid-state reaction of anhydrous chromium(III) tetrachloride (CrCl3) and sodium azide (NaN3) at a temperature of 600 degrees C for 12 h. The X-ray diffraction pattern of the product is indexed as cubic CrN. Transmission electron microscope images indicate that the sample consists of CrN nanorods with the diameters of 40-60 nm and lengths in the range of 500 nm to 1 mu m. X-ray photoelectron spectroscopy (XPS) results show the mole ratio of Cr:N as 1.15:1. The possible reaction mechanism is also discussed. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 4
页数:4
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