Self-assembled monolayers of isocyanides on nickel electrodes

被引：15
|
作者：
Lee, YG
Morales, GM
Yu, LP
机构：
[1] Univ Chicago, Dept Chem, Chicago, IL 60637 USA
[2] Univ Chicago, James Franck Inst, Chicago, IL 60637 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 27期
关键词：
chemisorption; molecular devices; monolayers; nickel; self-assembly;
D O I：
10.1002/anie.200500942
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Alligator clip on a nickel electrode: Monolayers of ferrocenyl-terminated isocyanides are strongly chemisorbed on nickel surfaces (see picture). The nickel-isocyanide interaction has a parallel binding mode, and the monolayers have higher thermal stability in boiling ethanol than thiol monolayers on gold. The nickel-isocyanide monolayers could be useful in molecular electronics. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：4228 / 4231
页数：4
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