Fabrication and mechanical/conductive properties of multi-walled carbon nanotube (MVNT) reinforced carbon matrix composites

被引:39
作者
Gao, XQ [1 ]
Liu, L
Guo, QG
Shi, JL
Zhai, GT
机构
[1] Chinese Acad Sci, Inst Coal Chem, Key Lab Carbon Mat, Taiyuan 030001, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
关键词
carbon nanotubes; mesophase pitch; heat treatment; mechanical properties; thermal conductivity;
D O I
10.1016/j.matlet.2005.05.021
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Multi-walled carbon nanotube (MWNT) reinforced carbon matrix (MWNT/C) composites have been explored using mesophase pitch as carbon matrix precursor in the present work. Results show that carbon nanotubes (CNTs)can enhance the mechanical properties of carbon matrix significantly. The maximal increment of the bending strength and stiffness of the composites, compared with the carbon matrix, are 147% and 400%, respectively. Whereas the highest in-plane thermal conductivity of the composites is 86 W m(-1) K-1 which much lower than that of carbon matrix (253 W m(-1) K-1). At the same time the electrical resistivity of the composites is much higher than that of matrix. It is implicated that CNTs seem to play the role of thermal/electrical barrier in the composites. FSEM micrograph of the fracture surface for the composites shows that the presence of CNTs restrains the crystallite growth of carbon matrix, which is one of factors that improve mechanical properties and decrease the conductive properties of the composites. The defects and curved shape of CNTs are also the affecting factors on the conductive properties of the composites. (C) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:3062 / 3065
页数:4
相关论文
共 18 条
[1]   Characterization of high thermal conductivity carbon fibers and a self-reinforced graphite panel [J].
Adams, PM ;
Katzman, HA ;
Rellick, GS ;
Stupian, GW .
CARBON, 1998, 36 (03) :233-245
[2]  
Andrews R, 2002, MACROMOL MATER ENG, V287, P395, DOI 10.1002/1439-2054(20020601)287:6<395::AID-MAME395>3.0.CO
[3]  
2-S
[4]  
[Anonymous], 2001, PHYS REV LETT, V87
[5]   Unusually high thermal conductivity of carbon nanotubes [J].
Berber, S ;
Kwon, YK ;
Tománek, D .
PHYSICAL REVIEW LETTERS, 2000, 84 (20) :4613-4616
[6]   An investigation of the sliding wear behavior of Cu-matrix composite reinforced by carbon nanotubes [J].
Dong, SR ;
Tu, JP ;
Zhang, XB .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2001, 313 (1-2) :83-87
[7]   HIGH THERMAL-CONDUCTIVITY RIBBON FIBERS FROM NAPHTHALENE-BASED MESOPHASE [J].
EDIE, DD ;
ROBINSON, KE ;
FLEUROT, O ;
JONES, SP ;
FAIN, CC .
CARBON, 1994, 32 (06) :1045-1054
[8]   The effect of processing on the structure and properties of carbon fibers [J].
Edie, DD .
CARBON, 1998, 36 (04) :345-362
[9]   Thermal conductivity of single-walled carbon nanotubes [J].
Hone, J ;
Whitney, M ;
Zettl, A .
SYNTHETIC METALS, 1999, 103 (1-3) :2498-2499
[10]   High-thermal-conductivity, mesophase-pitch-derived carbon foams: effect of precursor on structure and properties [J].
Klett, J ;
Hardy, R ;
Romine, E ;
Walls, C ;
Burchell, T .
CARBON, 2000, 38 (07) :953-973