Nitration of benzyl derivatives of acetylated hexaazaisowurtzitane

被引：0
|
作者：
Kulagina, Daria A. [1 ]
Goryaev, Artem S. [1 ]
Chernyshov, Ivan N. [1 ]
Sysolyatin, Sergey V. [1 ]
机构：
[1] Russian Acad Sci, Inst Problems Chem & Energet Technol, Siberian Branch, Biisk 659322, Russia
来源：
MENDELEEV COMMUNICATIONS | 2022年 / 32卷 / 03期
关键词：
hexaazaisowurtzitanes; cage compounds; nitration; nitrating mixtures; benzyl groups; selective reaction;
D O I：
10.1016/j.mencom.2022.05.019
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Nitration of N-benzylated 2,4,6,8,10,12-hexaazaisowurtzitane derivatives occurs selectively at para-positions of the benzyl groups. The best reagent for this reaction is ammonium nitrate in sulfuric acid.
引用
收藏
页码：349 / 350
页数：2
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