Visible-light-induced photocatalytic azotrifluoromethylation of alkenes with aryldiazonium salts and sodium triflinate

被引：108
|
作者：
Yu, Xing-Long [1 ]
Chen, Jia-Rong [1 ]
Chen, Dong-Zhen [1 ]
Xiao, Wen-Jing [1 ,2 ]
机构：
[1] Cent China Normal Univ, Coll Chem, Minist Educ, CCNU uOttawa Joint Res Ctr,Key Lab Pesticide & Ch, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China
[2] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 53期
关键词：
PHOTOREDOX-CATALYZED TRIFLUOROMETHYLATION; VICINAL DIFUNCTIONALIZATION; DIAZONIUM SALTS; FUNCTIONALIZATION; ARYL; CYCLOADDITION; FLUORINE; RADICALS; AMINOTRIFLUOROMETHYLATION; HYDROTRIFLUOROMETHYLATION;
D O I：
10.1039/c6cc03335k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The efficient visible light photocatalytic azotrifluoromethylation of alkenes with aryldiazonium salts and sodium triflinate is described, which gave the corresponding trifluoromethylated azo compounds in generally good yields. The trifluoromethylated azo products can be easily transformed into useful heterocycles and nitrogen-containing building blocks.
引用
收藏
页码：8275 / 8278
页数：4
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