Application of [Pyridine-1-SO3H-2-COOH]Cl as an efficient catalyst for the preparation of hexahyroquinolines

被引：26

作者：

Moosavi-Zare, Ahmad Reza ^{[1
]}

Afshar-Hezarkhani, Hadis ^{[1
]}

机构：

[1] Sayyed Jamaleddin Asadabadi Univ, Dept Chem, Asadabad 6541861841, Iran

来源：

EURASIAN CHEMICAL COMMUNICATIONS | 2020年 / 2卷 / 04期

关键词：

Pyridinium-1-sulfonic acid-2-carboxylic acid chloride; Hexahydroquinoline; multi-component condensation; beta-ketoester; solvent-free; ONE-POT SYNTHESIS; SOLVENT-FREE CONDENSATION; SULFONIC-ACID-CHLORIDE; POLYHYDROQUINOLINE DERIVATIVES; TRITYL CHLORIDE; MULTICOMPONENT SYNTHESIS; HETEROGENEOUS CATALYST; CARBOCATIONIC SYSTEM; HANTZSCH REACTION; ALDEHYDES;

D O I：

10.33945/SAMI/ECC.2020.4.5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pyridinium-1-sulfonic acid-2-carboxylic acid chloride {[Pyridine-1-SO3H-2-COOH]Cl} was synthesized and applied as a novel and efficient catalyst for the preparation of hexahydroquinolines by the one-pot multi-component condensation reaction of various aryl aldehydes with dimedone (5,5-dimethylcyclohexane-1,3-dione), beta-ketoesters and ammonium acetate under mild and solvent-free conditions. Low cost, non toxic nature, simple work-up and excellent yields of products are the main advantages of this work.

引用

页码：465 / 474

页数：10

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