Simplified models for SnO2 sensors during chemical and thermal transients in mixtures of inert, oxidizing and reducing gases

被引:49
作者
Fort, Ada
Mugnaini, Marco
Rocchi, Santina
Serrano-Santos, M. Belen
Vignoli, Valerio
Spinicci, Roberto
机构
[1] Univ Siena, Dept Informat Engn, I-53100 Siena, Italy
[2] Univ Florence, Dipartimento Energet, I-50139 Florence, Italy
来源
SENSORS AND ACTUATORS B-CHEMICAL | 2007年 / 124卷 / 01期
关键词
electronic nose; metal oxide sensors; tin oxide sensors; carbon monoxide; temperature modulation; parametric model;
D O I
10.1016/j.snb.2006.12.030
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this work, a set of models able to predict the behavior of tin oxide (SnO2) sensors during chemical and thermal transients is presented. These models are obtained through simplification of more complex physicochemical ones, taking into account both the intrinsic behavior of the sensors, observable during the exposure to an inert gas, and the extrinsic one, responsible for the sensor response in the presence of oxidizing and reducing gases. In particular, three simple models were developed, one for the intrinsic behavior, one for operation in oxygen (O-2), and one for operation in the presence of carbon monoxide (CO) and an inert gas. Finally, a complete model for operations in mixtures of CO and O-2 was derived from these latter. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:245 / 259
页数:15
相关论文
共 14 条
  • [1] Conduction model of metal oxide gas sensors
    Barsan, N
    Weimar, U
    [J]. JOURNAL OF ELECTROCERAMICS, 2001, 7 (03) : 143 - 167
  • [2] Bârsan N, 2003, J PHYS-CONDENS MAT, V15, pR813, DOI 10.1088/0953-8984/15/20/201
  • [3] Simulation of thin film gas sensors kinetics
    Brynzari, V
    Korotchenkov, G
    Dmitriev, S
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 1999, 61 (1-3): : 143 - 153
  • [4] Surface state trapping models for SnO2-based microhotplate sensors
    Ding, JH
    McAvoy, TJ
    Cavicchi, RE
    Semancik, S
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2001, 77 (03) : 597 - 613
  • [5] CO sensing with SnO2-based thick film sensors:: Surface state model for conductance responses during thermal-modulation
    Fort, A.
    Rocchi, S.
    Serrano-Santos, M. B.
    Mugnaini, M.
    Vignoli, V.
    Atrei, A.
    Spinicci, R.
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2006, 116 (1-2) : 43 - 48
  • [6] FORT A, 2006, P IEEE IMTC 2006 INS
  • [7] Surface state model for conductance responses during thermal-modulation of SnO2-based thick film sensors:: Part I -: Model derivation
    Fort, Ada
    Rocchi, Santina
    Serrano-Santos, M. Belen
    Spinicci, Roberto
    Vignoli, Valerio
    [J]. IEEE TRANSACTIONS ON INSTRUMENTATION AND MEASUREMENT, 2006, 55 (06) : 2102 - 2106
  • [8] Surface state model for conductance responses during thermal-modulation of SnO2-based thick film sensors:: Part II -: Experimental verification
    Fort, Ada
    Mugnaini, Marco
    Rocchi, Santina
    Serrano-Santos, M. Belen
    Spinicci, Roberto
    Vignoli, Valerio
    [J]. IEEE TRANSACTIONS ON INSTRUMENTATION AND MEASUREMENT, 2006, 55 (06) : 2107 - 2117
  • [9] CO sensing with SnO2 thick film sensors:: role of oxygen and water vapour
    Hahn, SH
    Bârsan, N
    Weimar, U
    Ejakov, SG
    Visser, JH
    Soltis, RE
    [J]. THIN SOLID FILMS, 2003, 436 (01) : 17 - 24
  • [10] Response model for thermally modulated tin oxide-based microhotplate gas sensors
    Ionescu, R
    Llobet, E
    Al-Khalifa, S
    Gardner, JW
    Vilanova, X
    Brezmes, J
    Correig, X
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 2003, 95 (1-3) : 203 - 211