Role of sintering aids in phase transformation, microstructure and mechanical properties of Si3N4/SiC nanocomposites

被引:1
作者
Yang, JF [1 ]
Ohji, T
Niihara, K
机构
[1] Japan Sci & Technol Corp JST, Synergy Mat Res Ctr, AIST, Moriyama Ku, Nagoya, Aichi 4638687, Japan
[2] Natl Inst Adv Ind Sci & Technol, Synergy Mat Res Ctr, AIST, Moriyama Ku, Nagoya, Aichi 4638687, Japan
[3] Osaka Univ, ISIR, Ibaraki, Osaka 5670047, Japan
关键词
ceramic nanocomposites; sintering aids; nucleation; phase transformation; grain growth; properties;
D O I
10.2109/jcersj.109.1275_920
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Details of alpha-->beta Si3N4 phase transformation, microstructural development and mechanical properties of SiC reinforced-Si3N4 matrix nanocomposites were investigated. Two sintering aid systems were used: 7.5 mass% MgAl2O4+7.5 mass% ZrO2 (MA-Z) and 10 mass% Y2O3+4 mass% Al2O3 (Y-A). The MA-Z system enhanced alpha-->beta phase transformation at low temperatures (1400-1550 degreesC), which was interpreted to arise from nucleation of beta -Si3N4 upon the SiC addition. This phenomenon was not observed in composites added with the Y-A system. Due to a large number of beta -Si3N4 nuclei, microstructure of Si3N4/SiC nanocomposites added with the MA-Z system exhibited a reduced grain growth and high flexural strength.
引用
收藏
页码:920 / 923
页数:4
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