Proton sponges and hydrogen transfer phenomena

被引：25
|
作者：
Pozharskii, Alexander F. [1 ]
Ozeryanskii, Valery A. [1 ]
机构：
[1] So Fed Univ, Dept Chem, Rostov Na Donu 344090, Russia
来源：
MENDELEEV COMMUNICATIONS | 2012年 / 22卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
X-RAY-DIFFRACTION; PERI-NAPHTHYLENEDIAMINES; MOLECULAR-STRUCTURE; BOND; 1,8-BIS(DIMETHYLAMINO)NAPHTHALENES; NAPHTHALENE; 5,6-BIS(DIMETHYLAMINO)ACENAPHTHYLENE; N-15; C-13; STABILIZATION;
D O I：
10.1016/j.mencom.2012.05.001
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Recent advances in the studies of hydrogen transfer (protonation, hydrogen bonding, hydride transfer and CH acidity) in proton sponges, its influence on the structure, stereodynamics and reactivity of these superbasic compounds and the use of the above phenomena for modelling enzyme catalysis have been discussed.
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页码：117 / 124
页数：8
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