A new water-soluble sulfonated cobalt(II) phthalocyanines: Synthesis, spectral, coordination and catalytic properties

被引：30

作者：

Vashurin, Artur ^{[1
]}

Filippova, Anna ^{[2
]}

Znoyko, Serafima ^{[3
]}

Voronina, Alena ^{[2
]}

Lefedova, Olga ^{[4
]}

Kuzmin, Ilya ^{[5
]}

Maizlish, Vladimir ^{[3
]}

Koifman, Oscar ^{[5
]}

机构：

[1] Ivanovo State Univ Chem & Technol, Dept Inorgan Chem, Ivanovo 153000, Russia

[2] Ivanovo State Univ Chem & Technol, Fac Fundamental & Appl Chem, Ivanovo 153000, Russia

[3] Ivanovo State Univ Chem & Technol, Dept Technol Fine Organ Synth, Ivanovo 153000, Russia

[4] Ivanovo State Univ Chem & Technol, Dept Phys & Colloid Chem, Ivanovo 153000, Russia

[5] Ivanovo State Univ Chem & Technol, Res Inst Macroheterocycles, Ivanovo 153000, Russia

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2015年 / 19卷 / 08期

基金：

俄罗斯科学基金会;

关键词：

sulfonated phthalocyanines; synthesis; aggregates; DABCO; catalyst; dye; AQUEOUS-SOLUTION; AGGREGATION; OXIDATION; TETRASULFOPHTHALOCYANINE; DERIVATIVES; COMPLEXES; KINETICS; PHOTOSENSITIZER; SUBSTITUENTS; DIMERIZATION;

D O I：

10.1142/S1088424615500753

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel complexes of cobalt(II) with sulfonated derivatives of phthalocyanines are synthesized. The influence of the sulfonated group's number in peripheral substituent on solubility of macrocycle and ability to form ordered structures in solution is showed. Transition from H-aggregates to monomeric phthalocyanine structures and sandwich-type dimers was found during formation of metallophthalocyanine complexes with 1,4-diazabicyclo[2.2.2]octane. The catalytic activity of metallophthalocyanines was studied on the model of Merox process.

引用

页码：983 / 996

页数：14

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