Crystallinity of block copolymer controlled by cyclodextrin

被引：4
作者：
Bertolino, Vanessa [1 ]
Cavallaro, Giuseppe [1 ]
Lazzara, Giuseppe [1 ]
Milioto, Stefana [1 ]
Parisi, Filippo [1 ]
机构：
[1] Univ Palermo, Dept Chem & Phys, Viale Sci,Pad 17, I-90128 Palermo, Italy
来源：
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2018年 / 132卷 / 01期
关键词：
Tetronic; DSC; Copolymer; Supramolecular structures; Cyclodextrin; MODIFIED HALLOYSITE NANOTUBES; ALPHA-CYCLODEXTRIN; TRIBLOCK COPOLYMERS; INCLUSION COMPLEXES; LIGHT-SCATTERING; PHASE-BEHAVIOR; AQUEOUS-MEDIA; NANOCOMPOSITES; POLYROTAXANES; TEMPERATURE;
D O I：
10.1007/s10973-018-6982-8
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
We report a differential scanning calorimetry study to investigate the effect of cyclodextrins (CD) on the crystallinity of a copolymer. Tetronics was selected as copolymer with star-like shape formed by four polyethylene oxide flanked by four polypropylene oxide blocks linked to ethylenediamine central group. The use of CD with different cavity size was exploited for a block selective inclusion. A model for supramolecular association was considered for a quantitative description of the enthalpy data. The polymer chain incorporation into the CD cavity generates a loss of crystallinity. The stoichiometry of the CD/copolymer aggregates can be tuned by changing the CD cavity size. The investigated systems represent interesting necklace-like supramolecular structures with tunable crystallinity.
引用
收藏
页码：191 / 196
页数：6
相关论文
共 45 条
[1]   Phase behavior of the Pluronic P103/water system in the dilute and semi- dilute regimes [J].
Alvarez-Ramirez, J. G. ;
Fernandez, V. V. A. ;
Macias, E. R. ;
Rharbi, Y. ;
Taboada, P. ;
Gamez-Corrales, R. ;
Puig, J. E. ;
Soltero, J. F. A. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2009, 333 (02) :655-662
[2]   Recent advances in the preparation of cyclodextrin-based polyrotaxanes and their applications to soft materials [J].
Araki, Jun ;
Ito, Kohzo .
SOFT MATTER, 2007, 3 (12) :1456-1473
[3]   Biopolymer-Targeted Adsorption onto Halloysite Nanotubes in Aqueous Media [J].
Bertolino, Vanessa ;
Cavallaro, Giuseppe ;
Lazzara, Giuseppe ;
Milioto, Stefana ;
Parisi, Filippo .
LANGMUIR, 2017, 33 (13) :3317-3323
[4]   Effect of the Biopolymer Charge and the Nanoclay Morphology on Nanocomposite Materials [J].
Bertolino, Vanessa ;
Cavallaro, Giuseppe ;
Lazzara, Giuseppe ;
Merli, Marcello ;
Milioto, Stefana ;
Parisi, Filippo ;
Sciascia, Luciana .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2016, 55 (27) :7373-7380
[5]   Thermal and thermo-oxidative degradations of poly(2,6-dimethyl-1,4-phenylene oxide) (PPO)/copoly(aryl ether sulfone) P(ESES-co-EES) block copolymers: a kinetic study [J].
Blanco, I. ;
Cicala, G. ;
Latteri, A. ;
Mamo, A. ;
Recca, A. .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2013, 112 (01) :375-381
[6]   Thermal study on phenyl, hepta isobutyl-polyhedral oligomeric silsesquioxane/polystyrene nanocomposites [J].
Blanco, Ignazio ;
Bottino, Francesco Agatino .
POLYMER COMPOSITES, 2013, 34 (02) :225-232
[7]   Cyclodextrin-threaded conjugated polyrotaxanes as insulated molecular wires with reduced interstrand interactions [J].
Cacialli, F ;
Wilson, JS ;
Michels, JJ ;
Daniel, C ;
Silva, C ;
Friend, RH ;
Severin, N ;
Samorì, P ;
Rabe, JP ;
O'Connell, MJ ;
Taylor, PN ;
Anderson, HL .
NATURE MATERIALS, 2002, 1 (03) :160-164
[8]   Polyethylene glycol/clay nanotubes composites Thermal properties and structure [J].
Cavallaro, G. ;
De Lisi, R. ;
Lazzara, G. ;
Milioto, S. .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2013, 112 (01) :383-389
[9]   Aqueous phase/nanoparticles interface: hydroxypropyl cellulose adsorption and desorption triggered by temperature and inorganic salts [J].
Cavallaro, G. ;
Lazzara, G. ;
Milioto, S. .
SOFT MATTER, 2012, 8 (13) :3627-3633
[10]   Steric stabilization of modified nanoclays triggered by temperature [J].
Cavallaro, Giuseppe ;
Lazzara, Giuseppe ;
Milioto, Stefana ;
Parisi, Filippo .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2016, 461 :346-351
12345