Synthesis and field emission properties of ZnCdO hollow micro-nano spheres

被引:31
作者
Li, Guangming [1 ]
Wang, Xinchang [1 ]
Wang, Yinghua [1 ]
Shi, Xinwei [1 ]
Yao, Ning [1 ]
Zhang, Binglin [1 ]
机构
[1] Zhengzhou Univ, Sch Phys & Engn, Key Lab Mat Phys, Zhengzhou 450052, Peoples R China
关键词
ZnCdO; hollow micro-nano spheres; growth mechanism; field emission;
D O I
10.1016/j.physe.2007.07.030
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The ZnCdO hollow micro-nano spheres have been achieved on the Si substrates without any catalysts using a simple thermal evaporation method. X-ray diffraction spectra confirm that the sample is a hexagonal wurtzite structure, and a little Cd doping would not change the crystal structures of ZnO. The growth mechanism of the ZnCdO hollow micro-nano spheres is deduced in detail. The PL spectra illustrate that Cd doping could induce the red-shift of optical band gap. Field emission measurements show a low turn-on field of similar to 1.86V/mu m at a current density of 1 mu A/cm(2). The emission current density reached 1 mA/cm(2) at an applied field of similar to 9.26 V/mu m. (C) 2008 Published by Elsevier B.V.
引用
收藏
页码:2649 / 2653
页数:5
相关论文
共 24 条
[1]   Modelling the shape and orientation of ZnO nanobelts [J].
Barnard, AS ;
Xiao, Y ;
Cai, Z .
CHEMICAL PHYSICS LETTERS, 2006, 419 (4-6) :313-316
[2]   High-performance ZnO nanowire field effect transistors [J].
Chang, Pai-Chun ;
Fan, Zhiyong ;
Chien, Chung-Jen ;
Stichtenoth, Daniel ;
Ronning, Carsten ;
Lu, Jia Grace .
APPLIED PHYSICS LETTERS, 2006, 89 (13)
[3]   Electrical and photoconductive properties of vertical ZnO nanowires in high density arrays [J].
Fan, Zhiyong ;
Dutta, Deepanshu ;
Chien, Chung-Jen ;
Chen, Hsiang-Yu ;
Brown, Evan C. ;
Chang, Pai-Chun ;
Lu, Jia G. .
APPLIED PHYSICS LETTERS, 2006, 89 (21)
[4]   Optical and structural analysis of ZnCdO layers grown by metalorganic vapor-phase epitaxy [J].
Gruber, T ;
Kirchner, C ;
Kling, R ;
Reuss, F ;
Waag, A ;
Bertram, F ;
Forster, D ;
Christen, J ;
Schreck, M .
APPLIED PHYSICS LETTERS, 2003, 83 (16) :3290-3292
[5]   Growth of ZnO nanotetrapods with hexagonal crown [J].
He, Fa-Quan ;
Zhao, Ya-Pu .
APPLIED PHYSICS LETTERS, 2006, 88 (19)
[6]   Temperature-dependent photoluminescence of quasialigned Al-doped ZnO nanorods [J].
He, H. P. ;
Tang, H. P. ;
Ye, Z. Z. ;
Zhu, L. P. ;
Zhao, B. H. ;
Wang, L. ;
Li, X. H. .
APPLIED PHYSICS LETTERS, 2007, 90 (02)
[7]  
Ivan M. S., 2006, APPL PHYS LETT, V89
[8]   Photoluminescence of ZnO nanowires grown on sapphire (1 1 (2)over-bar-0) substrates [J].
Jeon, Kyung Ah ;
Son, Hyo Jeong ;
Kim, Chang Eun ;
Kim, Jong Hoon ;
Lee, Sang Yeol .
PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 2007, 37 (1-2) :222-225
[9]   Necktie-like ZnO nanobelts grown by a self-catalytic VLS process [J].
Jian, J. K. ;
Wang, Cong ;
Zhang, Z. H. ;
Chen, X. L. ;
Xu, L. H. ;
Wang, T. M. .
MATERIALS LETTERS, 2006, 60 (29-30) :3809-3812
[10]   Indium-doped zinc oxide nanobelts [J].
Jie, JS ;
Wang, GZ ;
Han, XH ;
Yu, QX ;
Liao, Y ;
Li, GP ;
Hou, JG .
CHEMICAL PHYSICS LETTERS, 2004, 387 (4-6) :466-470