The reaction of ethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate with fullerene C-60

被引：2

作者：

Goldshleger, NF ^{[1
]}

Astakhova, AS ^{[1
]}

Lobach, AS ^{[1
]}

Boiko, GN ^{[1
]}

Denisov, NN ^{[1
]}

Nadtochenko, VA ^{[1
]}

Roshchupkina, OS ^{[1
]}

Shulga, YM ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INST STRUCT MACROKINET,CHERNOGOLOVKA 142432,MOSCOW REGION,RUSSIA

来源：

RUSSIAN CHEMICAL BULLETIN | 1996年 / 45卷 / 10期

关键词：

fullerene C-60; 1,4-dihydropyridines; Hantsch ester; dehydrogenation; laser photolysis; H-1 NMR spectroscopy;

D O I：

10.1007/BF01435392

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heating (100 degrees C, toluene) or photolysis (Nd3+ : YAG laser, lambda = 532 nm, benzonitrile) of a mixture of ethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate (Hantsch ester) (1) and fullerene C-60 under anaerobic conditions results in the formation of fullerene hydrogenation products and ethyl 2,6-dimethylpyridine-3,5-dicarboxylate, which is the product of dehydrogenation of 1, identified by IR spectroscopy and mass spectrometry. The triplet state of C-60 is quenched by the Hantsch ester.

引用

页码：2402 / 2404

页数：3

共 50 条

[41] Synthesis, aromatization and crystal structure of diether 4-(3,4-methylene dioxylphenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate under microwave irradiation
Tu, SJ
Miao, CB
Gao, Y
Feng, YJ
Shi, DQ
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2002, 21 (02) : 222 - 226
[42] Diethyl 2,6-dimethyl-4-[5-(4-nitrophenyl)-2-furyl]-1,4-dihydropyridine-3,5-dicarboxylate
Vrábel, V
Fronc, M
Svoboda, I
Marchalín, T
Baumlová, B
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O3592 - O3594
[43] 4-(2,3-dichlorophenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-bis(methoxycarbonyl),4-(2,4-dichlorophenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-bis(methoxycarbonyl), and 4-(2,3,5-trichlorophenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-bis(methoxycarbonyl): conformational observations in the crystalline state
Caignan, GA
Holt, EM
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2000, 30 (10) : 677 - 684
[44] 4-(2,3-Dichlorophenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-bis(methoxycarbonyl), 4-(2,4-dichlorophenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-bis(methoxycarbonyl), and 4-(2,3,5-trichlorophenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-bis(methoxycarbonyl): conformational observations in the crystalline state
Gregori A. Caignan
Elizabeth M. Holt
Journal of Chemical Crystallography, 2000, 30 : 677 - 684
[45] Diethyl 2,6-dimethyl-4-(5-phenyl-1H-pyrazol-4-yl)-1,4-dihydropyridine-3,5-dicarboxylate
Fun, Hoong-Kun
Ooi, Chin Wei
Malladi, Shridhar
Shivananda, K. N.
Isloor, Arun M.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O892 - U3336
[46] Diisopropyl 1-(4-methoxyphenyl)-2,6-dimethyl-4-(3-nitrophenyl)-1,4-dihydropyridine-3,5-dicarboxylate
Kapoor, Kamini
Gupta, Vivek K.
Kant, Rajni
Pawar, Milind P.
Joshi, Hitendra S.
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2979 - U874
[47] STRUCTURE OF DIETHYL 2,6-DIMETHYL-4-[5-(4-METHYLPHENYL)-2-FURYL]-1,4-DIHYDROPYRIDINE-3,5-DICARBOXYLATE
LOKAJ, J
VRABEL, V
SIVY, P
KETTMANN, V
ILAVSKY, D
JECNY, J
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1991, 47 : 886 - 888
[48] (R*)-(-)-3-[4-(benzyloxy)benzoylmethyl] 5-ethyl 2,6-dimethyl-4-(3-nitrophenyl)-1,4-dihydropyridine-3,5-dicarboxylate
Wu, Xiao-Yun
Hu, Ai-Xi
Cao, Gao
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O4578 - U3873
[49] 3-(benzotriazol-1-yl) 5-ethyl 2,6-dimethyl-4-(3-nitrophenyl)-1,4-dihydropyridine-3,5-dicarboxylate ethyl acetate hemisolvate
Sun, Feng-Xia
Fu, De-Cai
Yu, Yi-Feng
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O4207 - O4208
[50] Diethyl 4-[5-(biphenyl-4-yl)-1H-pyrazol-4-yl]-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate ethanol monosolvate
Fun, Hoong-Kun
Hemamalini, Madhukar
Vijesh, A. M.
Isloor, Arun M.
Arulmoli, T.
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O1768 - U1371

← 1 2 3 4 5 →