The reaction of ethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate with fullerene C-60

被引：2

作者：

Goldshleger, NF ^{[1
]}

Astakhova, AS ^{[1
]}

Lobach, AS ^{[1
]}

Boiko, GN ^{[1
]}

Denisov, NN ^{[1
]}

Nadtochenko, VA ^{[1
]}

Roshchupkina, OS ^{[1
]}

Shulga, YM ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INST STRUCT MACROKINET,CHERNOGOLOVKA 142432,MOSCOW REGION,RUSSIA

来源：

RUSSIAN CHEMICAL BULLETIN | 1996年 / 45卷 / 10期

关键词：

fullerene C-60; 1,4-dihydropyridines; Hantsch ester; dehydrogenation; laser photolysis; H-1 NMR spectroscopy;

D O I：

10.1007/BF01435392

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heating (100 degrees C, toluene) or photolysis (Nd3+ : YAG laser, lambda = 532 nm, benzonitrile) of a mixture of ethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate (Hantsch ester) (1) and fullerene C-60 under anaerobic conditions results in the formation of fullerene hydrogenation products and ethyl 2,6-dimethylpyridine-3,5-dicarboxylate, which is the product of dehydrogenation of 1, identified by IR spectroscopy and mass spectrometry. The triplet state of C-60 is quenched by the Hantsch ester.

引用

页码：2402 / 2404

页数：3

共 12 条

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