Thermodynamic properties of the solid solution Tb2O3•2ZrO2

被引:0
作者
Guskov, V. N. [1 ]
Gagarin, P. G. [1 ]
Tyurin, A., V [1 ]
Guskov, A., V [1 ]
Gavrichev, K. S. [1 ]
机构
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Leninskii Pr 31, Moscow 119991, Russia
基金
俄罗斯基础研究基金会;
关键词
Tb2O3 center dot 2ZrO(2); Molar heat capacity; Thermodynamic properties; CENTER-DOT 2ZRO(2); THERMAL-CONDUCTIVITY; MAGNETIC-PROPERTIES; IONIC-CONDUCTIVITY; PHASE-EQUILIBRIA; PYROCHLORE; ND2ZR2O7; SAMARIUM; FLUORITE; OXIDES;
D O I
10.1016/j.tca.2020.178596
中图分类号
O414.1 [热力学];
学科分类号
摘要
The temperature dependence for molar heat capacity of the solid solution Tb2O3 center dot 2ZrO(2) has been determined by adiabatic calorimetry (6-340 K). Based on the smoothed values of molar heat capacity, thermodynamic functions of Tb2O3 center dot 2ZrO(2) have been calculated without regard for very low temperature (< 6 K) magnetic transformations. The studies have been performed on samples characterized by chemical, phase and electron microscopy analyses.
引用
收藏
页数:4
相关论文
共 50 条
  • [31] Phase relations in the ZrO2-Sm2O3-Y2O3-Al2O3 system: experimental investigation and thermodynamic modelling
    Fabrichnaya, Olga
    Savinykh, Galina
    Zienert, Tilo
    Schreiber, Gerhard
    Seifert, Hans J.
    INTERNATIONAL JOURNAL OF MATERIALS RESEARCH, 2012, 103 (12) : 1469 - 1487
  • [32] Phase equilibria investigations and thermodynamic modeling of the Eu2O3-La2O3 and Eu2O3-La2O3-ZrO2 systems
    Qu, Gang
    Zhou, Jingkai
    Huang, Dandan
    JOURNAL OF ALLOYS AND COMPOUNDS, 2025, 1010
  • [33] Preparation and properties of Li2O-La2O3-ZrO2-P2O5 glass ceramics for potential solid electrolyte applications
    Luo, Zhiwei
    Qin, Chunchun
    Liang, Haozhang
    Liu, Taoyong
    Lu, Anxian
    SOLID STATE IONICS, 2019, 332 : 77 - 85
  • [34] ZrO2–Sc2O3 Solid Electrolytes Doped with Yb2O3 or Y2O3
    E. E. Lomonova
    D. A. Agarkov
    M. A. Borik
    G. M. Eliseeva
    A. V. Kulebyakin
    I. E. Kuritsyna
    F. O. Milovich
    V. A. Myzina
    V. V. Osiko
    A. S. Chislov
    N. Yu. Tabachkova
    Russian Journal of Electrochemistry, 2020, 56 : 118 - 123
  • [35] Electrical properties of ZrO2-Gd2O3 ceramics
    Dutta, S
    Bhattacharya, S
    Agrawal, DC
    MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2003, 100 (02): : 191 - 198
  • [36] Phase relationship in Gd2O3-Nd2O3-ZrO2 system at 1673 K and 1873 K
    Xu, Kai
    Zheng, Taowen
    Che, Xuezhen
    Su, Liumei
    Huang, Dandan
    CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2024, 87
  • [37] y ZrO2-Sc2O3 Solid Electrolytes Doped with Yb2O3 or Y2O3
    Lomonova, E. E.
    Agarkov, D. A.
    Borik, M. A.
    Eliseeva, G. M.
    Kulebyakin, A. V.
    Kuritsyna, I. E.
    Milovich, F. O.
    Myzina, V. A.
    Osiko, V. V.
    Chislov, A. S.
    Tabachkova, N. Yu.
    RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2020, 56 (02) : 118 - 123
  • [38] Phase diagram and thermodynamic properties of compounds in the SrO-SrF2-Mn2O3-O2 system
    M. L. Kovba
    Yu. Ya. Skolis
    Russian Journal of Physical Chemistry A, 2011, 85 : 2057 - 2061
  • [39] Phase Diagram and Thermodynamic Properties of Compounds in the SrO-SrF2-Mn2O3-O2 System
    Kovba, M. L.
    Skolis, Yu Ya
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 85 (12) : 2057 - 2061
  • [40] Effect of doping location induced anisotropy on thermophysical properties of dilute Fe2O3-Y2O3-ZrO2 solid solutions
    Guo, Fangwei
    Zhang, Xing
    Cai, Huangyue
    Fan, Xiaohui
    Hu, Li
    Sun, Wei
    Zhao, Xiaofeng
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2021, 104 (09) : 4742 - 4758