Thermodynamic properties of the solid solution Tb2O3•2ZrO2

被引:0
|
作者
Guskov, V. N. [1 ]
Gagarin, P. G. [1 ]
Tyurin, A., V [1 ]
Guskov, A., V [1 ]
Gavrichev, K. S. [1 ]
机构
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Leninskii Pr 31, Moscow 119991, Russia
基金
俄罗斯基础研究基金会;
关键词
Tb2O3 center dot 2ZrO(2); Molar heat capacity; Thermodynamic properties; CENTER-DOT 2ZRO(2); THERMAL-CONDUCTIVITY; MAGNETIC-PROPERTIES; IONIC-CONDUCTIVITY; PHASE-EQUILIBRIA; PYROCHLORE; ND2ZR2O7; SAMARIUM; FLUORITE; OXIDES;
D O I
10.1016/j.tca.2020.178596
中图分类号
O414.1 [热力学];
学科分类号
摘要
The temperature dependence for molar heat capacity of the solid solution Tb2O3 center dot 2ZrO(2) has been determined by adiabatic calorimetry (6-340 K). Based on the smoothed values of molar heat capacity, thermodynamic functions of Tb2O3 center dot 2ZrO(2) have been calculated without regard for very low temperature (< 6 K) magnetic transformations. The studies have been performed on samples characterized by chemical, phase and electron microscopy analyses.
引用
收藏
页数:4
相关论文
共 50 条
  • [21] Electrical properties of phases in the ZrO2 - Y2O3 - La2O3 system
    A. V. Zyrin
    A. V. Shevchenko
    L. M. Lopato
    Powder Metallurgy and Metal Ceramics, 2000, 39 : 146 - 150
  • [22] Transient and steady states of Gd2Zr2O7 and 2ZrO2•Y2O3 (ss) interactions with calcium magnesium aluminium silicates
    Duluard, Sandrine
    Delon, Elodie
    Bonino, Jean-Pierre
    Malie, Andre
    Joulia, Aurelien
    Bianchi, Luc
    Gomez, Philippe
    Ansart, Florence
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2019, 39 (04) : 1451 - 1462
  • [23] Effect of Gd2O3 Addition on the Microstructure and Properties of Gd2O3-Yb2O3-Y2O3-ZrO2 (GYYZO) Ceramics
    Gao, Pei-Hu
    Zeng, Sheng-Cong
    Jin, Can
    Zhang, Bo
    Chen, Bai-Yang
    Yang, Zhong
    Guo, Yong-Chun
    Liang, Min-Xian
    Li, Jian-Ping
    Li, Quan-Ping
    Lu, Yong-Qing
    Jia, Lu
    Zhao, Dan
    MATERIALS, 2021, 14 (23)
  • [24] Phase Equilibria in the ZrO2-La2O3-Sm2O3 System at 1100°C
    Korniienko, O. A.
    Bykov, A. I.
    Andrievskaya, E. R.
    POWDER METALLURGY AND METAL CERAMICS, 2020, 59 (3-4) : 224 - 231
  • [25] Microstructures and mechanical properties of Gd2Zr2O7/ZrO2(3Y) ceramics
    Ma, Lei
    Ma, Weimin
    Sun, Xudong
    Ji, Lianyong
    Liu, Jianan
    Hang, Kai
    JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 644 : 416 - 422
  • [26] Mass spectrometric study of thermodynamic properties in the Yb2O3-ZrO2 system at high temperatures
    Stolyarova, Valentina L.
    Lopatin, Sergey I.
    Fabrichnaya, Olga B.
    Shugurov, Sergey M.
    RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2014, 28 (01) : 109 - 114
  • [27] Defect chemistry of pyrochlore Pr2O3-ZrO2 system: the relevant thermodynamic parameters
    Abrantes, J. C. C.
    Gomes, E.
    Shlyakhtina, A. V.
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2024,
  • [28] Thermodynamic Properties of p-Sm2Zr2O7
    Gagarin, P. G.
    Tyurin, A. V.
    Guskov, V. N.
    Khoroshilov, A. V.
    Nikiforova, G. E.
    Gavrichev, K. S.
    INORGANIC MATERIALS, 2017, 53 (06) : 619 - 625
  • [29] Phase formation, crystal chemistry, and properties in the system Bi2O3-Fe2O3-Nb2O5
    Lufaso, Michael W.
    Vanderah, Terrell A.
    Pazos, Ileana M.
    Levin, Igor
    Roth, Robert S.
    Nino, Juan C.
    Provenzano, Virgil
    Schenck, Peter K.
    JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (12) : 3900 - 3910
  • [30] Oxygen-ion conductivity and mechanical properties of Lu2O3-doped ZrO2 as a solid electrolyte
    Park, Min-sung
    Jo, Kanghee
    Lee, Hwanseok
    Yoon, Bola
    Lee, Heesoo
    CERAMICS INTERNATIONAL, 2021, 47 (15) : 20844 - 20849