New halogenation reagent system for one-pot conversion of alcohols into iodides and azides

被引：14
|
作者：
Kamal, A [1 ]
Ramesh, G [1 ]
Laxman, N [1 ]
机构：
[1] Indian Inst Chem Technol, Div Organ Chem, Hyderabad 500007, Andhra Pradesh, India
来源：
SYNTHETIC COMMUNICATIONS | 2001年 / 31卷 / 06期
关键词：
D O I：
10.1081/SCC-100103316
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In situ generation of hydrogen iodide from methane-sulphonic acid/sodium iodide in different solvents was found to be an attractive reagent system for the chemoselective conversion of various alcohols to their corresponding iodides. Moreover, treatment of benzylic and allylic alcohols with this reagent system, followed by substitution with azide ion, produced the corresponding azides in one pot in good yields.
引用
收藏
页码：827 / 833
页数：7
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