Squaric Acid Catalyzed Highly Efficient Three-Component Mannich-Type Reaction

被引:7
作者
Azizi, Najmadin [1 ]
Davoudpour, Anahita [1 ]
机构
[1] Chem & Chem Engn Res Ctr Iran, Tehran, Iran
关键词
Green chemistry; Mannich reaction; Squaric acid; Novel organocatalyst; SURFACTANT-COMBINED CATALYST; IONIC LIQUID; AMINES; WATER; DERIVATIVES; ALDEHYDES; KETONES; SYSTEM;
D O I
10.1007/s10562-011-0669-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Squaric acid catalyzed three-component Mannich reaction of aromatic aldehydes, aromatic amines and cyclic ketones in water and solvent-free conditions at room temperature. This protocol has several advantages such as good yields, mild conditions, novel organocatalyst, and good anti selectivities.
引用
收藏
页码:1506 / 1510
页数:5
相关论文
共 44 条
[1]   HCl-catalyzed stereoselective Mannich reaction in H2O-SDS system [J].
Akiyama, T ;
Matsuda, K ;
Fuchibe, K .
SYNLETT, 2005, (02) :322-324
[2]  
Arend M, 1998, ANGEW CHEM INT EDIT, V37, P1044, DOI 10.1002/(SICI)1521-3773(19980504)37:8<1044::AID-ANIE1044>3.0.CO
[3]  
2-E
[4]   One-pot synthesis of dithiocarbamates accelerated in water [J].
Azizi, N ;
Aryanasab, F ;
Torkiyan, L ;
Ziyaei, A ;
Saidi, MR .
JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (09) :3634-3635
[5]   Highly efficient one-pot three-component Mannich reaction in water catalyzed by heteropoly acids [J].
Azizi, N ;
Torkiyan, L ;
Saidi, MR .
ORGANIC LETTERS, 2006, 8 (10) :2079-2082
[6]   Highly chemoselective addition of amines to epoxides in water [J].
Azizi, N ;
Saidi, MR .
ORGANIC LETTERS, 2005, 7 (17) :3649-3651
[7]   Novel and efficient method for the silylation of hydroxyl groups with hexamethyldisilazane (HMDS) under solvent-free and neutral conditions [J].
Azizi, N ;
Saidi, MR .
ORGANOMETALLICS, 2004, 23 (06) :1457-1458
[8]   Efficient Friedel-Crafts alkylation of indoles and pyrrole with enones and nitroalkene in water [J].
Azizi, Najmedin ;
Arynasab, Fezzeh ;
Saidi, Mohammad R. .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2006, 4 (23) :4275-4277
[9]   Polymer-supported organic catalysts [J].
Benaglia, M ;
Puglisi, A ;
Cozzi, F .
CHEMICAL REVIEWS, 2003, 103 (09) :3401-3429
[10]   Catalyst-free chemoselective N-tert-butyloxycarbonylation of amines in water [J].
Chankeshwara, Sunay V. ;
Chakraborti, Asit K. .
ORGANIC LETTERS, 2006, 8 (15) :3259-3262