Self-assembly of organic dyes in supramolecular aggregates

被引:122
作者
Heyne, Belinda [1 ]
机构
[1] Univ Calgary, Dept Chem, 2500 Univ Dr NW, Calgary, AB T2N 1N4, Canada
基金
加拿大创新基金会; 加拿大自然科学与工程研究理事会;
关键词
DIPOLAR MEROCYANINE DYES; ACRIDINE-ORANGE; ENERGY-TRANSFER; SPECTRAL SIGNATURES; AQUEOUS-SOLUTION; INDUCED EMISSION; PI-STACKS; J-BAND; EQUILIBRIUM; DIMERIZATION;
D O I
10.1039/c6pp00221h
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Many scientists probably consider dye aggregation in solution a curse. Here, the adjective "many" should be stressed, as some other researchers thrive on forcing dyes to aggregate in solution. This perspective paper is certainly not meant to be a comprehensive review on the topic. However, for people intrigued by this pervasive phenomenon, I will try to offer a general picture on the self-assembly of dyes into supramolecular aggregates by presenting and discussing key information on their thermodynamics, kinetics, and optical changes. More recent topics will be introduced, such as the impact of external stimuli on dye aggregation, with a particular focus on ion specific effects. Finally, aggregation-induced emission will also be examined.
引用
收藏
页码:1103 / 1114
页数:12
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