Block copolymers containing organic semiconductor segments by RAFT polymerization

被引：41
作者：
Chen, Ming [1 ]
Haeussler, Matthias [1 ]
Moad, Graeme [1 ]
Rizzardo, Ezio [1 ]
机构：
[1] CSIRO Mat Sci & Engn, Clayton, Vic, Australia
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2011年 / 9卷 / 17期
关键词：
FRAGMENTATION-CHAIN TRANSFER; LIVING RADICAL POLYMERIZATION; MEDIATED POLYMERIZATION; REGIOREGULAR POLYTHIOPHENE; INITIALIZATION BEHAVIOR; DIBLOCK COPOLYMER; POLYMERS; H-1-NMR; 2-VINYLTHIOPHENE; FLUORESCENCE;
D O I：
10.1039/c1ob05276d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Approaches to the synthesis of block copolymers containing organic semiconductor segments (polythiophene, perylene diimide) by RAFT polymerization have been explored. A method involving transformation of a vinyl derivative to a macro-RAFT agent provides for the synthesis of block copolymers which are joined by a short non-hydrolysable linkage.
引用
收藏
页码：6111 / 6119
页数：9
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