Laser-assisted production of tricalcium phosphate nanoparticles from biological and synthetic hydroxyapatite in aqueous medium

被引:21
作者
Boutinguiza, M. [1 ]
Pou, J. [1 ]
Lusquinos, F. [1 ]
Comesana, R. [1 ]
Riveiro, A. [1 ]
机构
[1] Univ Vigo, Dept Fis Aplicada, Vigo 36310, Spain
关键词
Nanoparticles; Calcium phosphate; Laser ablation; BONE; BIOCERAMICS; MORPHOLOGY; ABLATION; SURFACE; PHASE;
D O I
10.1016/j.apsusc.2010.12.004
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Pulsed laser ablation technique has attracted great attention as a method for preparing nanoparticles. In this work, calcined fish bones and synthetic hydroxyapatite, have been used as target to be ablated in de-ionized water with a pulsed CO2 laser to produce calcium phosphate nanoparticles. The obtained nanoparticles were amorphous and spherical in shape with a mean diameter of about 25 nm. The microanalyses revealed that nanoparticles obtained from the synthetic HA undergo transformation to tricalcium phosphate. While nanoparticles obtained from the biological hydroxyapatite mostly preserve the composition of precursor material. (C) 2010 Elsevier B. V. All rights reserved.
引用
收藏
页码:5195 / 5199
页数:5
相关论文
共 30 条
[1]   Nanostructured bioceramics for maxillofacial applications [J].
Adamopoulos, Othon ;
Papadopoulos, Triantafillos .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 2007, 18 (08) :1587-1597
[2]   Laser ablation synthesis in solution and size manipulation of noble metal nanoparticles [J].
Amendola, Vincenzo ;
Meneghetti, Moreno .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 11 (20) :3805-3821
[3]  
[Anonymous], J BIOMED MAT RES B
[4]  
[Anonymous], 1994, J MAT SCI MAT MED, DOI DOI 10.1007/BF00058956
[5]   Wettability patterning of hydroxyapatite nanobioceramics induced by surface potential modification [J].
Aronov, D ;
Rosenman, G ;
Karlov, A ;
Shashkin, A .
APPLIED PHYSICS LETTERS, 2006, 88 (16)
[6]   MACROPARTICLE DISTRIBUTION AND CHEMICAL-COMPOSITION OF LASER-DEPOSITED APATITE COATINGS [J].
BAGRATASHVILI, VN ;
ANTONOV, EN ;
SOBOL, EN ;
POPOV, VK ;
HOWDLE, SM .
APPLIED PHYSICS LETTERS, 1995, 66 (19) :2451-2453
[7]   Production of microscale particles from fish bone by gas flow assisted laser ablation [J].
Boutinguiza, M. ;
Lusquinos, E. ;
Comesana, R. ;
Riveiro, A. ;
Quintero, F. ;
Pou, J. .
APPLIED SURFACE SCIENCE, 2007, 254 (04) :1264-1267
[8]   Hydroxylapatite nanoparticles obtained by fiber laser-induced fracture [J].
Boutinguiza, M. ;
Lusquinos, F. ;
Riveiro, A. ;
Comesana, R. ;
Pou, J. .
APPLIED SURFACE SCIENCE, 2009, 255 (10) :5382-5385
[9]   Comparison of amorphous TCP nanoparticles to micron-sized α-TCP as starting materials for calcium phosphate cements [J].
Brunner, Tobias J. ;
Bohner, Marc ;
Dora, Claudio ;
Gerber, Christian ;
Stark, Wendelin J. .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART B-APPLIED BIOMATERIALS, 2007, 83B (02) :400-407
[10]   Effect of particle size, crystal phase and crystallinity on the reactivity of tricalcium phosphate cements for bone reconstruction [J].
Brunner, Tobias J. ;
Grass, Robert N. ;
Bohner, Marc ;
Stark, Wendelin J. .
JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (38) :4072-4078