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Sandwich-Structured, Hydrophobic, Nanocellulose-Reinforced Polyvinyl Alcohol as an Alternative Straw Material
被引:21
作者:
Chou, Chun-Tu
[1
]
Shi, Shih-Chen
[1
]
Chen, Chih-Kuang
[2
]
机构:
[1] Natl Cheng Kung Univ NCKU, Dept Mech Engn, Tainan 70101, Taiwan
[2] Natl Sun Yat Sen Univ, Dept Mat & Optoelect Sci, Kaohsiung 80424, Taiwan
来源:
关键词:
sandwich structure;
hydrophobic;
polyvinyl alcohol;
cellulose;
straw;
PLA BLOCK-COPOLYMER;
POLY(VINYL ALCOHOL);
MECHANICAL-PROPERTIES;
ACID-HYDROLYSIS;
ELASTIC-MODULUS;
CELLULOSE;
POLYMERS;
BLENDS;
FTIR;
D O I:
10.3390/polym13244447
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
An environmentally friendly, hydrophobic polyvinyl alcohol (PVA) film was developed as an alternative to commercial straws for mitigating the issue of plastic waste. Nontoxic and biodegradable cellulose nanocrystals (CNCs) and nanofibers (CNFs) were used to prepare PVA nanocomposite films by blade coating and solution casting. Double-sided solution casting of polyethylene-glycol-poly(lactic acid) (PEG-PLA) + neat PLA hydrophobic films was performed, which was followed by heat treatment at different temperatures and durations to hydrophobize the PVA composite films. The hydrophobic characteristics of the prepared composite films and a commercial straw were compared. The PVA nanocomposite films exhibited enhanced water vapor barrier and thermal properties owing to the hydrogen bonds and van der Waals forces between the substrate and the fillers. In the sandwich-structured PVA-based hydrophobic composite films, the crystallinity of PLA was increased by adjusting the temperature and duration of heat treatment, which significantly improved their contact angle and water vapor barrier. Finally, the initial contact angle and contact duration (at the contact angle of 20 degrees) increased by 35% and 40%, respectively, which was a significant increase in the service life of the biodegradable material-based straw.
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页数:24
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