Principles of mononucleating and binucleating ligand design

被引：498

作者：

Gavrilova, AL ^{[1
]}

Bosnich, B ^{[1
]}

机构：

[1] Univ Chicago, Dept Chem, Chicago, IL 60637 USA

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 02期

关键词：

D O I：

10.1021/cr020604g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The design of binucleating ligands, which formed bimetallic complexes, and the characteristics of chelate rings were analyzed. The bimetallic complexes were constructed without ligands bridging the two metals. Two planar metal complexes were held apart by rigid molecular spacers. Five membered chelate rings were considered the most stable. Crystal structures of the bisporphyrin ligand complexes showed that cosiderable distortion of the metalloporphyrin rings could be tolerated. The separation between the ligand planes was found flexible.

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页码：349 / 383

页数：35

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