Separation of group five elements by reversed-phase chromatography

被引:6
作者
Wilk, P. A. [1 ]
Landrum, J. H. [1 ]
Shaughnessy, D. A. [1 ]
Kenneally, J. M. [1 ]
Stoyer, N. J. [1 ]
Stoyer, M. A. [1 ]
Moody, K. J. [1 ]
Aksenov, N. V. [2 ]
Bozhikov, G. A. [2 ]
Tereshatov, E. E. [2 ]
Vostokin, G. K. [2 ]
Shishkin, S. V. [2 ]
Dmitriev, S. N. [2 ]
机构
[1] Lawrence Livermore Natl Lab, Livermore, CA 94551 USA
[2] Joint Inst Nucl Res, Flerov Lab Nucl React, Dubna 141980, Moscow Region, Russia
基金
俄罗斯基础研究基金会; 美国能源部;
关键词
CHEMISTRY; TANTALUM; PA; TA; NB;
D O I
10.1007/s10967-007-7127-x
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A chemical separation method based on reversed-phase chromatography has been developed to separate the group five elements from the reaction products produced in the bombardment of Am-243 with Ca-48 ions. Decontamination factors on the order of 10(6) were achieved for group-three elements such as americium, and 10(7) or more for selected reaction products as measured by gamma-ray spectrometry pre- and post-chemistry. Details of the chemical separation scheme are discussed and compared to previously reported results.
引用
收藏
页码:651 / 657
页数:7
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