Atmospheric oxidation of a Nb-Zr alloy studied with XPS

被引:74
作者
Olsson, COA [1 ]
Landolt, D [1 ]
机构
[1] Ecole Polytech Fed Lausanne, MXC Ecublens, Inst Mat, Lab Met Chim, CH-1015 Lausanne, Switzerland
关键词
atmospheric corrosion; XPS; zirconium; niobium;
D O I
10.1016/S0010-938X(03)00139-2
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The long term atmospheric oxidation of a Nb-Zr alloy was studied by XPS. Curve fit parameters were defined and strictly constrained to obtain a consistent evaluation of film thickness and chemistry. A formalism was introduced to distinguish between the water, hydroxide and oxide contributions to the surface oxide. Ageing experiments were carried out simultaneously exposing one lot of samples to a laboratory atmosphere for 10 months and a second lot to a dry atmosphere in a desiccator. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:213 / 224
页数:12
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