Molar excess Gibbs free energy of 1-propanol or 2-propanol plus aromatic hydrocarbons at 298.15 K in terms of an association model with a Flory contribution term

被引:26
作者
Gupta, V [1 ]
Maken, S [1 ]
Kalra, KC [1 ]
Singh, KC [1 ]
机构
[1] MAHARSHI DAYANAND UNIV,DEPT CHEM,ROHTAK 124001,HARYANA,INDIA
关键词
aromatic hydrocarbons; association model; flory contribution term; Gibbs free energy of mixing;
D O I
10.1016/0040-6031(95)02745-9
中图分类号
O414.1 [热力学];
学科分类号
摘要
Molar excess Gibbs free energy of mixing values for 1-propanol or 2-propanol + benzene, toluene, o- m- or p-xylene at 298.15 K have been calculated by the Barker method from vapour pressure data measured by a static method. The free energies of mixing for these binary systems are also predicted in terms of the Mecke-Kempter type of association model with a Flory contribution term using two interaction parameters. The predicted values agree reasonably well with the experimental values.
引用
收藏
页码:187 / 198
页数:12
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